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  • Chemistry  (98)
  • AIRCRAFT DESIGN, TESTING AND PERFORMANCE  (2)
  • 1970-1974  (79)
  • 1915-1919  (21)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 52 (1919), S. 1249-1255 
    ISSN: 0365-9631
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 51 (1918), S. 1571-1587 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 706-716 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This is a study of materials which are positive-temperature-coefficient resistors. Such materials, composed of conductive particles dispersed in a crystalline polymeric matrix, have been found to be of limited stability. An example is carbon black in high-density polyethylene. On repeated cycling through the anomaly temperature or on extensive heating at or above the anomaly temperature, the room temperature resistivity rises and the anomaly height falls to zero. This phenomenon has been shown to be caused by the absorption of oxygen by the polymer matrix which alters the structure, reduces the crystallinity, and induces an unusual form of crosslinking of a reversible nature.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 2079-2089 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Commercial triblock polymers (Kratons) consisting of polystyrene and a polydiene were characterized via gel permeation chromatography and small-angle x-ray scattering in order to determine the amount of free polystyrene and diblock material and to clarify the effect of these polymeric impurities on the morphology of solvent-cast samples. Gel permeation chromatography measurements revealed the Kratons to consist of 80-85% triblock, 15-20% diblock, and trace amounts of free polystyrene. Pure triblocks, impurity-doped pure triblocks, the Kratons, and a postpolymerically degraded Kraton were examined with regard to the effect of polymeric impurities on morphology. Small amounts (〈5%) of free polystyrene induce a regularization of the glassy domains, while increased amounts of this homopolymer apparently lead to diffuse phase boundaries. The presence of diblock polymer results in a loss of macrolattice details, indicating the presence of less ordered and more diffuse glassy domains.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 462-468 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It has been shown that the only way to predict the size of the PTC effect displayed by a crystalline polymer when filled with conductive particles is through the knowledge of the glass transition point of the polymer. The size of the PTC anomaly is found to decrease sharply with rise in glass transition temperature and for a polymer to be a useful PTC material its glass transition must be below 0°C. It has not been possible to explain this relationship by any of the current theories of the PTC mechanism in filled polymers.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 108 (1919), S. 303-317 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 109 (1919), S. 1-30 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A. Es wurden folgende Methoden zur Darstellung des Gadoliniums geprüft: 1Die Alkalidoppelsulfatmethode.Die Methode erweist sich zur Darstellung des Gadoliniums nur bedingt als brauchbar. Ihre unbequeme Handhabung verbietet eine erschöpfende Anwendung zur Darstellung einer Einzelerde. Dagegen vermag sie gut Dienste zu leisten, wenn es sich darum handelt, ein umfangreiches schwachgadoliniumhaltiges Material in zwei Teile zu teilen, in deren einem man das Gadolinium konzentrieren kann.2Die Hydrazindoppelsulfatmethode.Diese Methode wurde neu ausgearbeitet; sie wirkt der Alkalidoppelsulfatemethode analog und in dem gleichen Sinne. Sie hat gegenüber jener den Vorzug, daß man die Menge der abzuscheidenden Erden in der Hand hat.Es werden die Hydrazindoppelsulfate einiger typischer Erden dargestellt und ihre Zusammensetzung durch Analyse ermittelt.3Die fraktionierte Kristallisation der Bromate.Diese von C. James zuerst angegebene Methode eignet sich in hervorragender Weise zur Trennung der Terbinerden von den Yttererden. Die Scheidung verläuft schnell und gestattet das Arbeiten in größtem Maßstabe, infolge der großen Löslichkeit und guten Kristallisationsfähigkeit der Bromate. Man kann jedoch mit ihr keine Trennung der Ceriterden von den Terbinerden erzielen, da die Löslichkeit des Gadoliniumbromats zwischen den Löslichkeiten von Samarium und Neodymbromat liegt. Die Methode muß also mit einer anderen, zur Abscheidung der Ceriterden dienenden verbunden werden.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 2435-2438 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 408 (1974), S. 15-20 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Notice on the Magnetic Behaviour of Li3CrO4Li3CrO4, a smaragd green powder, is due to powder photographs (Guinier-Simon-technique) isotypic with orthorhombic HT—Li3PO4, a = 6.309, b = 10.851, c = 4.952 Å, Z = 4. Between 298 and 10K the Curie-Weiss-Law is obeyed with μ=1.60 B.M. and Θ=+10 K. Below 5 K ferromagnetism is observed. ESR measurements at 4.2 K and more pronounced at 1.8 K show anisotropy of the ligand field.
    Notes: Li3CrO4, ein smaragdgrünes Pulver, ist nach Guinier-Simon-Aufnahmen isotyp mit HT-Li3PO4, a = 6,309 Å, b = 10,851 Å, c = 4,952 Å, Z = 4. Zwischen 298 und 10 K wird das Curie-Weisssche Gesetz mit μ=1,60 B.M., Θ=+10K befolgt. Unterhalb von 5 K tritt überraschend Ferromagnetismus auf. ESR-Messungen bei 4,2 K und ausgeprägter bei 1,8 K zeigen eine Anisotropie des Ligandenfeldes.
    Additional Material: 5 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 408 (1974), S. 275-282 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Dinitrito Cobalt(III) Complexes. I. Preparation and Absorption Spectra of Di(ethylenediamine) Cobalt(III) PerchloratesCis and trans dinitrito diethylenediamine cobalt perchlorates could be prepared starting with carbonato and trans dichloro ethylenediamine cobalt perchlorate. Spectroscopic data are reported and compared with those of the corresponding dinitro complexes.
    Notes: Ausgehend von Carbonato- und trans-Dichloro-diäthylendiaminkobalt(III)-perchlorat konnten cis- und trans-Dinitrito-diäthylendiamin-kobalt(III)-perchlorate dargestellt werden. Ihre Spektren im sichtbaren Gebiet und UV werden mitgeteilt und mit den Spektren der entsprechenden Dinitrokomplexe verglichen.
    Additional Material: 2 Ill.
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