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  • Chemical Engineering  (336)
  • Physics  (296)
  • Analytical Chemistry and Spectroscopy  (235)
  • Cell & Developmental Biology
  • GENERAL
  • 1970-1974  (1,022)
  • 1955-1959  (133)
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Keywords
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Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 415-416 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 445-454 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The fundamental vibrational frequencies of an isolated chain of cis-1,4-polybutadiene have been calculated. Infrared and polarized Raman data are used in the force constant refinement routine. The assignments of the vibrational frequencies are discussed in terms of the potential energy distribution.
    Additional Material: 5 Ill.
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  • 3
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acrylonitrile (AN) was graft-polymerized onto gelatinized cationic starch (CS) possessing diethylaminoethyl ether groups by cerium (IV) initiation to give stable latexlike copolymer dispersions. Dispersions of the latex copolymers, having up to 50% grafted polyacrylonitrile (PAN), air- and heat-dry on glass to clear, adhesive films. Sonification of up to 8% dispersions at 20 Khz reduced their viscosities from 1500-3000 cP to 15-40 cP. Scanning electron microscopy revealed that both nonsonified and sonified dispersions consist of ball-like particles measuring about 0.05-0.15 μ in diameter when dry. The films are formed by coalescence of these particles. The degree to which AN grafts onto CS at ambient temperature is related to the nitrogen content of CS, gelatinization time of CS at 95°C, sequence of AN and cerium(IV) addition, concentration of cerium (IV), concentration of AN, and severity of reaction agitation. Number-average molecular weight values of PAN were about 106 when grafting was conducted under stirring and about 5 × 105 when conducted under shaking action.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 1213-1224 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthetic details of solution polymerization in benzene and bulk polymerization of vinylferrocene are reported. In benzene solutions, with azobisisobutyronitrile (AIBN) as the initiator, small yields of low-polydispersity low molecular weight (M̄n ≃ 5000) polyvinylferrocene is obtained. However, high yields can be obtained by continuous or multiple AIBN addition. Higher molecular weight polymers and binodal polymers can be obtained as the monomer concentration is increased. In bulk polymerizations, yields of 80% can be obtained. The molecular weight increases as temperature decreases from 80 to 60°C in bulk polymerizations, and an increasing amount of insoluble polymer results. The soluble portion is often binodal, the higher molecular weight node consisting of an increasingly branched structure. Lower molecular weight polymer was readily fractionated into narrow fractions from benzene-methanol systems, but higher molecular weight polymer proved impossible to fractionate into narrow fractions due to branching.
    Additional Material: 3 Ill.
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  • 5
    Publication Date: 2019-06-27
    Keywords: GENERAL
    Type: NASA-CR-126424 , Am. Assoc. for Advan. of Sci. Mariner to Mars; 4 p
    Format: text
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  • 6
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Development of the secondary palate in Swiss white mouse embroyos was studied from age nine-and-one-half days in utero to the stage of mesenchymal coalescence in the secondary palate (approximately fifteen-and-one-half days). The greatest changes observed occur in the mesenchyme. At early stages, mesenchymal cells underlying oral ectoderm of the head are few and only occasionally contact the ectoderm. Electron micrographs show large intercellular spaces between the ectodermal cells. As embryogenesis continues, the mesenchymal cells become more numerous, closer to each other and closer to the epithelium. Just prior to horizontal transposition of shelves, the mesenchymal cells spread farther from each other and from the palatal epithelium and epithelium of the palatal tip becomes stretched. Ultrastructurally the intercellular spaces between epithelial cells of the palate tip have become much smaller. Some mitochondria in some epithelial cells are swollen and have clear matrices and distorted cristae. The shelves become horizontal and meet in the midpalate. Cells with degeneration bodies are seen in the epithelial seam. The seam undergoes autolysis and is replaced by mesenchyme. The morphological changes described, particularly in the mesenchyme, may play an important role in determining the effect of various teratogens at different stages of palatal development. The changes in both mesenchyme and epithelial cells in the later stages may constitute part of the process of preparing shelves for fusion as postulated by Pourtois ('66).
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 869-882 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystallization kinetics of a high molecular weight fraction of linear polyethylene was studied in dilute solutions of p-xylene, n-hexadecane, and decalin by dilatometric methods. For all solvents and temperatures, the experimental isotherms could be quantitatively described by the Avrami formulation for the complete transformation. This result is unique in the realm of polymer crystallization, since marked deviations from this theory are usually observed in more concentrated systems. The Avrami exponent is found to be n = 4 in all cases. The temperature coefficients of the rate constants are indicative of a nucleation controlled process. The data fit either a two-dimensional or three-dimensional nucleation mode, and a discrimination can not be made between these two cases. The interfacial free energies are found to be independent of the solvent medium. It is also shown that, irrespective of the type of nucleation control governing the kinetics, the same type governs the crystallite thickness of the lamella-like crystals that are formed.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 379-383 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is made of diffusion and chemical reaction in an isothermal multicomponent fluid. Transient gas-phase reaction in a one-dimensional nonflow system and steady state gas-phase or surface reaction in a tubular reactor are considered. The equations are linearized around some state away from equilibrium. Multicomponent and binary diffusivity expressions are used and a series of reactions of varying complexity is considered. The possibility of oscillations increases as the complexity of the reactions is increased. These oscillations occur with time in the nonflow system and with space-time in the tubular reactor, and it appears that any reacting mixture which oscillates in one of these two systems will also oscillate in the other.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 689-696 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interaction of macromixing and micromixing in microbiological flow reactors based on a kinetic model of the Michaelis-Menten type has been treated by considering two general types of flow systems: the system of n continuous stirred-tank reactors in series (n-CSTR's in series) and the series combination of a plug-flow reactor and a continuous stirred-tank reactor. Systematic schemes to describe the micromixing conditions of a reactor system are presented. Additional micromixing states are considered besides those proposed by Kramers and those proposed by Zwietering if the systems are employed as empirical models of a flow system. When the number of stirred-reactor units in the system of n-CSTR's in series is small, micromixing has a significant effect on the growth processes. As the number of reactor units increases, the micromixing effect on the growth processes decreases. The effect of micromixing is also important for a system described by a series combination of a plug-flow reactor and a continuous stirred reactor. In addition, the exit concentrations from the system having the same residence time distribution and the same degree of segregation may be different from each other. Information obtained in this study is pertinent in the design of biological flow reactors and sewage treatment systems.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 1268-1271 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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