ISSN:
0570-0833
Schlagwort(e):
Chirality functions
;
Optical activity
;
Allene derivatives
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
A comparison of calculated and experimental data shows that the optical rotatory power of phenylallenecarboxylic acids is quantitatively described by the polynomial expression developed in (1). The Td component of this expression, the only relevant one for the case of methane derivatives turns out to be negligibly small in the case of allene derivatives. Therefore, and because allene derivatives belong to category a[16] the sequence of the λ-parameter values of the ligands may be used to determine the configuration and the sign of rotation.
Zusätzliches Material:
7 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/anie.197300201
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