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  • Chemistry  (3,074)
  • SPACE VEHICLES  (765)
  • Analytical Chemistry and Spectroscopy
  • 1970-1974  (2,124)
  • 1965-1969  (1,715)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Berichte über Tagungen und Messen (1972)
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 3 (1972), S. 98-103 
    Details
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mawe.19720030212
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  • 2
    Electronic Resource
    Electronic Resource
    Structure of boromycin95th Comm. of the series Metabolic Products of Microorganisms. -94th comm.: [1]. (1971)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 1709-1713 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The structure II of boromycin C45H74BNO15 (cf. [2]) has been established by combination of chemical evidence with X-ray analysis. The antibiotic is a D-valine ester of a Böeseken-complex of boric acid with a macrodiolide of a new type.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19710540624
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  • 3
    Electronic Resource
    Electronic Resource
    A cooperative molecular weight distribution test (1973)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 269-282 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The development of gel permeation chromatography (GPC) has provided a convenient tool for the rapid determination of molecular weight distribution. The question has arisen as to the suitability of the method for specification purposes. The present work, suggested by the Naval Air Systems Command, represents an attempt to assess the precision of the method through a series of tests carried out by a number of laboratories using identical procedures on the same samples. Ten laboratories agreed to take part. Naval Ordnance Station, Indian Head, worked out standard conditions for operation of the chromatograph, for calibration of the columns, and for analysis of the GPC curves. Two samples of polystyrene were used by the various organizations for calibration of their instruments. Number-average molecular weight, heterogeneity index, and cumulative molecular weight distribution curves were determined on four samples of carboxyl-terminated polybutadiene (CTPB) and two samples of hydroxyl-terminated polybutadiene (HTPB), all unidentified except by letter code. All laboratories used identical directions for setting up CTPB and HTPB calibration curves which were based on curves determined from vapor-pressure osmometer molecular weights and GPC count numbers of fractionated material. Variation among the different laboratories was 0.15 in heterogeneity index, and a maximum of 1200 in molecular weight provided one aberrant set of values was eliminated. The six samples had heterogeneity indices from 1.15 to 1.54, while molecular weight varied from approximately 3000 to 6000. The average coefficient of variation of the molecular weight values was 6.2 ± 0.7%, which is quite acceptable. Variation in heterogeneity index was too great for specification purposes when considered among the different laboratories, but may be sufficiently good when measured by any one laboratory.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1973.070170121
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  • 4
    Electronic Resource
    Electronic Resource
    A valid method of calibration which includes correction for dispersion in gel permeation chromatography (1972)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 3353-3360 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two independently derived distribution function methods validate both the calibration curve and the dispersion correction of the “effective linear calibration” method used in gel permeation chromatography (GPC). Experimental conditions are specified for making the method more useful by permitting linear extrapolation of the calibration line, \documentclass{article}\pagestyle{empty}\begin{document}$ V_R = C_1 + C_2 \log M, $\end{document} and for using a minimum number of standards. The independent methods quantitatively relate known differential of integral distribution functions for standard samples to their respective chromatograms. As such, they are useful calibration methods also, but are limited in scope and range.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1972.070161224
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  • 5
    Electronic Resource
    Electronic Resource
    Modifications to the Mackereth oxygen electrode (1967)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 9 (1967), S. 623-625 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260090415
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  • 6
    Electronic Resource
    Electronic Resource
    Steady state multiplicity and stability of enzymatic reaction systems (1973)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 15 (1973), S. 1131-1145 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Several techniques for investigating the multiplicity and stability of open isothermal enzymatic reactors are discussed and some of the pitfalls in previous thinking pointed out. The example which is used to illustrate these methods exhibits several interesting features. Among these is the existence of a stable oscillatory state which surrounds a unique steady state which is asymptotically stable to certain finite disturbances.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260150611
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  • 7
    Electronic Resource
    Electronic Resource
    Gram-Scale purification of arginine, formylmethionione, glutamic acid and phenylalanine transfer ribonucleic acids from E. coli K-12 MO7Research sponsored by the National Institute of General Medical Sciences, National Institutes of Health under contract with the United States Atomic Energy Commission and Union Carbide Corporation, Nuclear Division. (1970)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 12 (1970), S. 889-912 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gram-sized quantities of purified arginine, formylmethionine, glutamic acid, and phenylalanine-2 tRNAs have been prepared from pools of E. coli K-12 MO7 mixed tRNAs by reversed-phase chromatography after preliminary fractionation on DEAE-cellulose. Purified formylmethionine tRNA and partially purified arginine tRNA and glutamie acid tRNA were obtained from large-scale RPC-3 runs (4 × 36 in. column). The arginine tRNA was further purified by rechromatography on RPC-4 columns, and the gluatmic acid tRNA by rechromatography on an RPC-3 column. Two phenylalanine tRNAs were resolved on large-scale (2 × 96 in. column) RPC-3 runs; only the second phenylalanine tRNA reached a satisfactory degree of activity. About 0.88 g of arginine tRNA, 70% activity; 3.32 g of formylmethionine tRNA, 97% activity; 0.80 g of glutamic acid tRNA, 83% activity and O.92 g of phenylalanine-2 tRNA, 78% activity, were produced. The processing steps employed are reliable and reproducible and the procedure is amenable to routine production of these tRNAs.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260120604
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  • 8
    Electronic Resource
    Electronic Resource
    The numerical solution of boundary-layer problems (1965)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 733-739 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method for numerical solution of boundary-layer problems has greater applicability as well as greater speed and accuracy than the several previously proposed methods. The method uses the Goertler-transformed equations and a nonlinear finite-difference procedure. In most earlier work on difference methods the equations have been linearized at each step parallel to the boundary. The method of treatment of the boundary conditions on the equation of change for energy or mass transfer is shown to have an important influence on accuracy, and a new, more accurate method of treating boundary conditions involving the normal derivative is presented.Typical complete solutions are compared with the several methods. The solutions include both similar and more general flows up to separation, as well as coupling between the momentum and energy-balance equations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690110432
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  • 9
    Electronic Resource
    Electronic Resource
    The electroinitiated polymerization of N-vinylcarbazole with zinc bromide, IIPart I: cf.12.. Kinetics of polymerization (1973)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 169 (1973), S. 177-189 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die elektroinitiierte Polymerisation von N-Vinylcarbazol (VCZ) wurde in Aceton bei 25°C mit Zinkbromid als Katalysator unter Verwendung von Platinelektroden eingehend untersucht. Die Polymerisationsgeschwindigkeit erwies sich als direkt abhängig von der Stromstärke, der Zinkbromid-Konzentration und dem anfänglichen Wassergehalt des Solvens.Die Molekulargewichte der entstandenen Polymeren (1000-6000) sind unabhängig von der Stromstärke, der Zinkbromid-Konzentration und dem Umsetzungsgrad des Monomeren zum Polymeren, werden jedoch beeinflußt durch Wasser, die Monomerkonzentration und das Elektrodenmaterial. Die chemische Zusammensetzung der Polymeren ändert sich nicht mit der Stromstärke, der Zinkbromid-Konzentration, dem Umsetzungsgrad und dem Elektrodenmaterial. Sie ändert sich jedoch ein wenig mit dem Wassergehalt des Acetons.
    Notes: The electroinitiated polymerization of N-vinylcarbazole (VCZ) in acetone solvent at 25°C with zinc bromide, as catalyst, and platinum electrodes was investigated in detail. The polymerization rate was found to be directly dependent on current strength, zinc bromide concentration and the initial water content of the solvent.The molecular weights of the formed polymers (1000-6000) are independent of current strength, zinc bromide concentration and degree of conversion of monomer to polymer, but are affected by water, monomer concentration, and by the type of electrodes used. The chemical composition of the polymer is invariant with current strength, zinc bromide concentration, degree of conversion, and electrode material but does vary slightly with the water content of acetone.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1973.021690117
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  • 10
    Electronic Resource
    Electronic Resource
    Phthalocyanin- und Perfluorphthalocyaninkomplexe von Thorium, Protactinium, Uran und Neptunium (1969)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 81 (1969), S. 913-913 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19690812233
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