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  • 1975-1979  (1)
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    Electronic Resource
    Electronic Resource
    The mechanism of the reaction between hydroxyl ions and some internally hydrogen-bonded acids (1976)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 8 (1976), S. 741-751 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the proton transfer between hydroxyl ions and phenylazoresorcinol, 4-(p-nitrophenylazo), and 4-(m-nitrophenylazo) resorcinol have been investigated at 25°C and an ionic strength of 0.1M, in a wider pH range than had been done by previous authors. The rate at first decreased with decreasing [OH-], reached a minimum, and then started to increase with decreasing [OH-]. This unusual effect is explained by a mechanism suggested earlier for tropaeolin O. Rate constants and equilibrium constants have been evaluated and discussed.The experimental data were obtained by the T-jump method.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550080509
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