ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Mechanical fracture of nylon 6 produces free radicals as a direct result of bond-breaking; these initial free radicals rapidly decay into secondary free radicals at room temperature. Aromatic nitro-compounds react with the initial, but not the secondary, free radicals. The rate of reaction is sufficiently fast to compete with the usual initial radical decay process, even at room temperature. Considerations involved in applying high speed (microsecond) electron spin resonance techniques are discussed.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760190211
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