ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The preparation of the nucleophile trans-[RuCl(NO)(1)], where 1 is the bidentate ligand Ph2PCH2C18CH2PPh2, and of the five-coordinate species [RuCl(CO)(NO)(1)], [RuCl(CO)(NO)(Ph2PCH2Ph)2] and [RuCl(NO)(2)(1)] are reported.The crystal structure of [RuCl(CO)(NO)(1)] shows that the coordination around the metal atom is distorted trigonal bipyramidal with the phosphorus atoms in axial positions. The Ru—N—O bond angle is 142.8°. 1H- and 31P-NMR. and \documentclass{article}\pagestyle{empty}\begin{document}$ \tilde \nu $\end{document}NO IR.-data for the above complexes are reported and related to the coordination geometry.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19790620712
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