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  • LUNAR AND PLANETARY EXPLORATION  (9)
  • Physics  (5)
  • PIC
  • Pisum
  • 1975-1979  (15)
  • 1
    Electronic Resource
    Electronic Resource
    The cytology of cotyledon cells and the induction of giant polytene chromosomes inPisum sativum (1979)
    Springer
    Protoplasma 101 (1979), S. 73-80 
    Details
    ISSN: 1615-6102
    Keywords: Cotyledon culture ; Pisum ; Polytene chromosomes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The cotyledon cells ofPisum sativum have high DNA contents. By appropriate culture techniques, some of these cells can be triggered into division. Two types of dividing nuclei were seen. Firstly those that were polyploid with metaphases containing chromosome numbers ranging in value from 4 x to 32 x. Included among these were unexpected numbers equivalent to 12 x and 14 x. Secondly there were cells containing giant polytene chromosomes and these progressed from prophase to a metaphase where the polytene chromosomes separated into constituent single chromosomes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01293436
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1563-1571 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a program to extend the range of donor-acceptor-initiated polymerization processes, the electroinitiation of 2-vinylnaphthalene in a zinc chloride-sulfolane solution has been studied. Good conversion yields of well-characterized (NMR, IR, GPC, elemental analysis) poly(vinylnaphthalene) were obtained with the process showing several mechanistic similarities to other donor-acceptor salt electropolymerization systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150704
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Electrochemically initiated polymerization of styrene with tetraalkyl and -aryl group VA halide support electrolytes (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1555-1562 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemically initiated polymerization of styrene in methylene chloride solvent with the use of platinum electrodes and tetraalkyl and -aryl group VA halides (i.e., quaternary ammonium, phosphonium, and arsonium compounds) as electrolyte has been investigated. The order of reactivity of the electrolytes with respect to polymerization rate and initiation efficiency was found to be: arsonium 〉 phosphonium 〉 ammonium. Mechanisms involving the electroreduction of the group VA quaternary halides to species capable of electroinitiating polymerization are postulated. The observed losses in solution conductivities during polymerization with the quaternary phosphonium and arsonium electrolytes indicate possible interaction between the initiating radical-ionic species and the supporting electrolyte. In an attempt to further elucidate the mechanism of initiation in these systems, a separate series of experiments, employing the nonpolymerizing monomer, 1,1-diphenylethylene, has been carried out.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150703
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  • 4
    Electronic Resource
    Electronic Resource
    The photo- and electroinitiated polymerization of N-vinyl phthalimide (1979)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 1153-1161 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: To elucidate mechanisms in electroinitiated polymerization reactions a comparison was conducted between ultraviolet (UV) photoinitiation and electroinitiation of N-vinyl phthalimide with zinc chloride as a catalyst. Both methods give low yields of a complex polymer product. A detailed analysis, infrared (IR), gel permeation chromatography (GPC), elemental, and molecular weight, conducted on the polymeric products, indicated that phthalimide ring opening was occurring and that complex mixtures of poly(N-vinyl phthalimide) derivatives were formed. Both initiation methods gave comparable results, which further indicated mechanistic similarity between photo-and electroinitiation in these donor-acceptor charge transfer polymerizations.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1979.170170419
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  • 5
    Electronic Resource
    Electronic Resource
    Photoinitiation and electroinitiation in the polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2673-2684 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The zinc chloride-catalyzed polymerization of 2-vinylnaphthalene (VN) with both photoinitiation and electronitiation methods was examined. Good yields were obtained with both methods, the electroinitiated process being somewhat faster. The mechanism for polymerization initiation was investigated through a detailed comparison of the kinetics. Both initiation methods show a similar response to increasing input energy and to change in salt to monomer mole ratio. Both methods indicate formation of a ZnCl2-(2-VN)2 complex as intermediate with the formation of the species being rate-determining. These results, together with other similar investigations, are then used to deduce a mechanism that involves the formation of an electronically excited donor-acceptor complex. It is argued that in certain salt-stabilized, electron-delocalized, aromatic systems, such excitation is possible in electroinitiation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170151112
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  • 6
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of arylvinyl monomers (1979)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 1411-1418 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electroinitiated polymerizations of styrene, 2-vinylnaphthalene, and 9-vinylanthracene were compared in sulfolane and acetone solvents in the presence of ZnCl2. The relative orders of polymerization rates and polymerization efficiencies, in both solvents, were 9-vinylanthracene 〉 2-vinylnaphthalene 〉 styrene, with faster rates and higher efficiencies occurring in sulfolane. Data obtained from viscosity and gel permeation chromatography (GPC) studies indicate that the molecular weights of the polymers produced in these systems are extremely low, 〈5000. Chemical composition and infrared (IR) spectral data suggest that abnormal transfer reactions (possibly from solvent) may be occurring in the electroinitiated 9-vinylanthracene polymerizations. The polymerization mechanism appears to be cationic in these monomer-solvent systems with ZnCl2.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1979.170170515
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  • 7
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    The relative humidity of Mars' atmosphere (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: As a general rule, Mars' atmosphere contains as much water vapor as it can hold on a daily basis; it reaches saturation at night, and the vapor appears to be distributed throughout the lowest several kilometers. Interesting exceptions to this occur when there are temperature inversions in the arctic springtime and during dust-storm activity. As contrasted to the northern hemisphere there appears to be no local source of water in the southern temperate and arctic areas.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 84; Dec. 30
    Format: text
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  • 8
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    The vertical distribution of Mars water vapor (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: Analysis of observations made from the Viking 1 Orbiter indicates that the water vapor over the Viking 1 landing site is uniformly mixed with the atmosphere and not concentrated near the surface. The analysis incorporates the effects of atmospheric scattering and explains why previous earth-based observations showed a strong diurnal variation in water content. It also explains the lack of an early morning fog and removes the necessity of daily exchange of large amounts of water between the surface and the atmosphere. A water vapor volume mixing ratio of 1.5 x 10 to the -4th is inferred for the Viking 1 site in late summer.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 84; June 10
    Format: text
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  • 9
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    Effects of dust on the heating of Mars' surface and atmosphere (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: An analysis performed to determine the effect dust particles suspended in Mars' atmosphere have on the radiation reaching the surface both directly and scattered by the dust is described. Additionally, the fraction of incident sunlight directly absorbed by the atmospheric dust is computed. These calculations are done for ranges of dust opacity, incidence angle, surface albedo, and dust albedo, representative of the conditions on Mars. The effect of atmospheric dust on the Bond albedo is discussed. It is shown that direct heating of the atmosphere by dust absorption of solar radiation is adequate to explain Mars' south polar spring temperature inversion. Under most circumstances the presence of dust in Mars' atmosphere produces a lowering of the average surface temperature; this is probably the cause of the anomalously slow south polar cap retreat of 1977. Explicit forms for both the surface heating and the atmospheric heating as a function of the dust opacity, incidence angle, surface albedo and dust albedo are given.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 84; Dec. 30
    Format: text
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  • 10
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    Viking: Mars atmospheric water vapor mapping experiment - Preliminary report of results (1976)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: Observations made from the Viking 1 orbiter show very little water vapor in the Mars atmosphere in the southern hemisphere (0 to 3 precipitable micrometers) with a gradual increase across the equator to northern latitudes. Maximum amounts between 20 and 30 micrometers have been observed in the short period covered by the observations to date. The season, northern midsummer, corresponds to the beginning of the water vapor cycle in that hemisphere. A strong repetitive diurnal cycling between the solid and vapor phase is observed at a site to the east of the Tharsis Ridge at 10 deg north latitude; the vapor lies close to the martian surface and is most probably in saturation equilibrium with a surface haze or fog throughout much of the day.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science; 193; Aug. 27
    Format: text
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