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  • Chemistry  (2)
  • 1975-1979  (2)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Properties of blends of poly(ethylene oxide) samples with different molecular weight: Kinetics of crystallization from melt (1979)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 219-228 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystallization kinetics of binary blends of samples of poly(ethylene oxide) with different molecular weights, namely 2000, 20 000, and 197000 has been investigated by means of polarized light microscopy in order to establish the dependence of the kinetic parameters upon the composition. The temperature and composition dependence of the growth rates of spherulites in thin films of supercooled melt has been analyzed by means of the theoretical expressions given by Hoffman and Lauritzen. The experimental results indicate that some kinetic and thermodynamic quantities such as the rate of crystallization, the equilibrium melting temperature, the free energy of formation of a nucleus of critical size, and the surface free energy of folding are strongly dependent upon the composition of the blends.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1979.021800121
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  • 2
    Electronic Resource
    Electronic Resource
    Properties of solution grown crystals of aliphatic polyesters with variable amount of double bonds along the chain (1979)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 1023-1035 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In order to elucidate the relations between morphological habits, thermal behaviour and chemical structure of polymers, aliphatic polyesters with variable amount of trans-double bonds along the backbone chain were crystallized from dilute solutions in 1-propanol and 1-butanol. The crystals were studied with electron microscopy, differential scanning calorimetry, and wide angle X-ray diffraction. The morphology of solution grown single crystals and some thermodynamic quantities such as the equilibrium dissolution and melting temperature and the enthalpy and entropy of fusion are influenced by the percentage of unsaturated comonomer. The thermal behaviour and the X-ray diffraction of these crystals suggest that saturated and unsaturated repeating units are able to cocrystallize.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1979.021800419
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    Paper (German National Licenses)
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