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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1973-1985 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Comparisons were made of differential scanning-calorimetric (DSC) thermograms of both liquid and powdered commercial phenol-formaldehyde resins. By a combination of the results from analyses under a variety of conditions, such as ambient pressure, high pressure, using freeze-dried samples, and also by direct observation of the resin-curing process in wood-veneer assemblies, the curing reactions of phenol-formaldehyde resins were found to differ for resol and novolac systems. At a heating rate of 10°C/min, the resol resin showed endothermic curing reactions at temperatures of about 150°C, while the novolac-type resin showed an exothermic peak maximum at about 160°C. Results are presented to show how DSC can be used to differentiate between a resol and novolac system.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 17 (1977), S. 436-439 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An ovrerview of a new theory for describing interfacial phenomena in layered composites is presented. Relations are given for determining the adhesion of thin brittle films on flexible substrates, for determining residual strains resulting from drying solvent cast films, and for calculating thermoelastic strains in unsymmetric laminates. An experimental technique to measure the adhesion is discussed and values are obtained using experimental data. Residual strains are also calculated using the derived relations and solvent d in data.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1189-1201 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of water vapor on a polyimide has been investigated in the temperature region of -190 to 325°C using an automated torsion pendulum. A damping peak, TH2O developes at -122°C (1 Hz) in the thermomechanical spectra of the polymer which is due to water-polymer interactions. The peak intensifies as the humidity of the conditioning atmosphere, at both 30° and at 325°C, increases and attains a limiting value at about 3000 ppmv H2O. The process is reversible. It is concluded that the number of sites in the polymer for interaction with water is low and limited (〈0.3 molecule H2O per polymer repeat unit) and, assuming direct proportionality between the intensity of the loss peak and the amount of water adsorbed, that the adsorption of water vapor follows the Langmuir isotherm.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 1619-1626 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A dual-calibration method for the determination of molecular weights and molecular weight distribution of styrene-maleic anhydride copolymers (S/MA) by gel permeation chromatography (GPC) is introduced. It might be applicable to copolymers of other type. A linear relationship of intrinsic viscosity [η] and weight-average molecular weight (M̄w) for unfractionated S/MA in tetrahydrofuran (THF) at 25°C can be expressed by the equation \documentclass{article}\pagestyle{empty}\begin{document}$ \left[ \eta \right] = 3.98 \times 10^{ - 4} \bar M_w^{0.596} . $\end{document} The maleic anhydride content of the copolymers ranges from 5 to 50 mole-%, and the M̄w range is from 2 × 104 to 7 × 106. The plot of log [η] M̄w versus GPC elution volume of the S/MA copolymers falls on the same curve as that of the polystyrene standards in THF.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 13 (1975), S. 761-765 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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