ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organic Lewis Acids, 331) The Photochemistry of Cyclic Acylals of Alkylidene-, Alkenylidene-, and Benzylidenemalonic AcidsThe photochemistry of the title compounds 1 resembles that of α,β-unsaturated esters. Observed reactions include deconjugation (→ 2), β, δ-cyclopropane ring closure(→ 4), and [2 + 2]-cycloaddition (→ 5, 7, 8) as well as ene-type addition to olefins (→ 9). Reaction mechanism and preparative aspects are discussed.
Notes:
Die Photochemie der Titelverbindungen 1 entspricht der von α,β-ungesättigten Estern: Dekonjugation zu 2, β,δ-Cyclopropanbildung (→ 4) und [2 + 2]-Cycloaddition (→ 5, 7, 8) sowie substituierende Addition an Olefine (→ 9) Reaktionsmechanismus und präparative Aspekte werden diskutiert.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19791121002
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