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  • Other Sources  (2)
  • ATOMIC AND MOLECULAR PHYSICS  (1)
  • FLUID MECHANICS AND HEAT TRANSFER  (1)
  • 1975-1979  (2)
  • 1
    Publication Date: 2011-08-17
    Description: Relative total scattering cross sections for normal H2 + normal H2, para-H2 + para-H2, normal D2 + normal D2, ortho-D2 + ortho-D2, and HD + HD were measured at energy below 10 meV by colliding particles from two inclined nozzle beams. Cross sections for the H2 + H2 pairs were measured over a relative velocity range of 200-1450 m/s; the normal H2 + normal H2 results suggest a l = 3 orbiting resonance near 375 m/s while the para-H2 + para-H2 results have a l = 4 orbiting resonance near 585 m/s. This latter resonance has a peak energy of 1.79 meV and a FWHM of 1.05 meV. The D2 + D2 cross sections were measured over the velocity range of 190 to 1000 m/s and a minimum between the l = 4 and l = 5 orbiting resonances was observed. Some preliminary measurements on HD + HD over the range of 250-1250 m/s indicate a possible l = 4 orbiting resonance near 300 m/s. The experimental work compares favorably to cross sections calculated from a theoretical potential.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Journal of Chemical Physics; 71; Dec. 1
    Format: text
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  • 2
    Publication Date: 2019-06-27
    Description: A generalized expression for the nonsteady-state parameter, lag-time, has been obtained from Fick's second law for gas-phase transport through hollow, cylindrical membranes. This generalized expression is simplified for three limiting cases of practical interest: (1) diffusion controlled transport, (2) phase boundary reaction control at the inlet surface, and (3) phase boundary reaction control at the outlet surface. In all three cases the lag-time expressions were found to be inversely proportional only to the diffusion coefficient and functionally dependent on the membrane radii. Finally, the lag-time expressions were applied to experimentally obtained lag-time data for alpha-phase titanium and alpha-phase iron.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: Metallurgical Transactions A - Physical Metallurgy and Materials Science; 6A; Feb. 197
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