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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 2065-2070 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In the complete absence of a systematic polymer nomenclature, a scheme of nomenclature based on structure is proposed. The problem of naming a “mer” has been solved for an addition polymer by adding “ne” to the monomer name, the justification being on withdrawal of a π bond a monomer becomes a mer. To furnish completeness to the nomenclature, condensation polymers were included in the system. The present nomenclature system of polymers is very arbitrary. Some polymers are not chemically named, some named incorrectly, and there are some fantastic names. After pointing these out, the possible solutions were shown, encompassing a systematic discussion on nearly every type of polymer-linear, branched, or crosslinked-and copolymer (including block or graft), and plastic, fiber, or rubber, and stereospecific polymer. One or more names were proposed for different cases.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 831-840 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Fiber-reinforced polymer composites show high specific strength and stiffness. The alignment of reinforcing fibers results in anisotropy of the material. This anisotropic behavior has been studied through dynamic mechanical analysis of unidirectional carbon fiber-reinforced polypropylene (CFRPP) composites measured in both parallel and transverse directions to fiber arrangement. Several parameters such as storage modulus (E′), loss modulus (E″), loss factor or damping factor (tan δ), and complex viscosity (MU*) have been determined over a wide range of frequencies and at a fixed temperature. Relaxation and retardation spectra have been constructed for these composites. Modulus enhancement occurs due to stiffness imparted by the fiber and efficient stress transfer at the interface. Relaxation of the polymer matrix ceases with increase in the volume fraction of the fibers. α′-relaxation is observed for the composite having a 13% volume fraction of fibers and is ascribed to relaxation in the crystalline phase where the additional crystallinity arises out of the transcrystalline growth at the fiber-matrix interface. There exists a good correlation between theroretical curves with the experimental ones. Relaxation and retardation spectra and the dynamic parameters determined for these composites show a good correlation with the volume fraction of fibers as well as the direction of the applied load. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 1603-1611 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymerization of natural rubber and MMA was carried out in the presence of Bz2O2 or AIBN as thermal initiator and hydrogen peroxide or benzophenone as photosensitizer. From the overall copolymerization product, the rubber-PMMA graft copolymer fraction was isolated from unreacted rubber and free PMMA fractions and composition characterization of the separated fractions was done by determination of rubber unsaturation. The efficiency of grafting under different conditions has been calculated and compared.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 15 (1971), S. 1599-1605 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In the present paper we have analytically derived a single-point equation for determining the intrinsic viscosity of a polymer. It is observed that the proposed equation gives a much better agreement with the extrapolated value of [η] over a wide range of concentration for good as well as poor polymer-solvent systems.
    Additional Material: 2 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 31 (1986), S. 747-762 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blending of nylon-6 and nylon-66 was carried out by coextrusion in the whole range of compositions with particular emphasis on small amounts of one polymer in the other. Most significant improvement in properties is achieved at low blend compositions in which the minor component remains amorphous while severely affecting the crystallization behavior of the major component. The nylon-6-rich blends crystallize predominantly in the γ-crystalline form, whereas the nylon-66-rich blends exhibit low crystallinity. Because of this property, the blends are more easily drawable, giving rise to a more highly oriented structure with improved tensile properties and uniformity. High tenacity and modulus are observed in drawn blends containing 70% nylon 6 and 30% nylon-66.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 183 (1982), S. 1093-1099 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: N-Vinylcarbazole (NVC) is polymerised in the presence of pyridine at 60°C by using azodiisobutyronitrile (AIBN) and benzoyl peroxide (Bz2O2) as initiators and the results are compared with those obtained when benzene is used as the solvent. In the AIBN-initiated system using pyridine as the solvent the rates of polymerisation follow an usual linear relationship with respect to monomer concentration and a square root dependence with respect to the initiator concentration. In the Bz2O2-initiated system, however, deviations from these ideal behaviours are observed when benzene and pyridine, respectively, are used as the solvent. Initiation occurs through the complexation of the monomer with Bz2O2 and degradative transfer is thought to be mainly responsible for this unusual kinetic behaviour.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 186 (1985), S. 2649-2656 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A unified study of the anomalous mechanical properties and birefringence of low density polyethylene (LDPE) is attempted within the frame work of the rotating element model. The present paper investigates the validity of the affine transformation rule used in the Ward model and suggests a modified affine law which is based on the consideration that the units are only reoriented and, unlike the affine law, are not deformed due to the uniaxial stretching. The relationship between the angles made by the C-axis of the unit with the drawing direction in the undrawn state (θ) and the drawn state (θ), is deduced as sin θ = f(n) sin θ′. From the birefringence data of different polymers a two parameter relation of the form f (n) = exp [-(n - 1)α/β] is suggested. Using this new orientation function, the agreement of the predicted values of E0 and E90 for LDPE for the entire draw ratio range between temperatures of 60°C to -125°C, is quite satisfactory. An interesting feature is that the abrupt change in the values of the parameters α and β at two different temperatures may be associated with a phase transition of LDPE at an intermediate temperature.
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 188 (1987), S. 217-226 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A phenomenological model is proposed which considers the polymer as an aggregate of units. The units are composed of two distinct phases  -  amorphous and crystalline. The thermal conductivity of a unit is calculated in terms of those of its constituents. In the undrawn state these units are distributed randomly, and the isotropic thermal conductivity of the bulk results. The development of strong anisotropy in thermal conductivity is explained in terms of the preferred orientation of these units. The structural features of this model are similar to those employed for the interpretation of the mechanical properties. The change in orientation of the units was deduced from the experimental data of birefringence. Finally, the results obtained from the composite model for several semicrystalline polymers are compared with the experimental data and other existing calculations. The model is found to give a fair overall description of the thermal conductivity in the cases of polypropylene, polyoxymethylene, low and high density polyethylene, and polychlorotrifluoroethylene.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 193 (1992), S. 31-41 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Benzoxazole-2-thiol (1)/dibenzoyl peroxide (Bz2O2) was used as photoinitiator for the polymerization of methyl methacrylate (MMA) in bulk and in solution. The study of initiator decomposition was conducted spectrophotometrically. Kinetic studies of the photopolymerization indicated the formation of a complex between 1 and Bz2O2 in the stoichiometric ratio 2:1. The initiation is believed to occur via in situ formation of bis(benzoxazol-2-yl) disulfide in the presence of light.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 186 (1985), S. 1593-1604 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Photopolymerization of methyl methacrylate (MMA) in bulk and in solution was studied using the combination benzil (BZL)/triethylamine (TEA) as photoinitiator. The initiation was found to occur through photoreduction of the ketone in presence of an amine via exciplex formation. A kinetic study of the polymerization showed that both carbonyl groups of benzil are involved in exciplex interaction, resulting in diradical formation. An analysis of the initiator dependent termination process revealed that primary radical termination is predominant in the particular system compared to the degradative initiator transfer. A kinetic scheme was designed to account for the various wastage reactions occurring in the polymerization system.
    Additional Material: 9 Ill.
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