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  • Inorganic Chemistry  (64)
  • Biochemistry and Biotechnology  (34)
  • Wiley-Blackwell  (98)
  • American Geophysical Union
  • PANGAEA
  • 1975-1979  (98)
Collection
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  • Wiley-Blackwell  (98)
  • American Geophysical Union
  • PANGAEA
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Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 18 (1976), S. 289-295 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of pH and temperature on the substrate yield coefficient for growth of Saccharomyces cerevisiae in a chemostat under limited organic substrate conditions was studied.Mathematical analysis of the substrate yield coefficient as a function of pH and temperature in the near-optimal area was made. It was shown that the location of pH and temperature optima were independent of each other. The maximum substrate yield coefficient had the following coordinates: pH = 4.1, temperature = 28.5°C.
    Additional Material: 1 Ill.
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  • 2
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Investigations on the Catalysis of Ammonia Synthesis and Nitrogen Isotope Exchange by Lamellar Compounds of Graphite with Iron, Ruthenium, and OsmiumThe catalytic activity of transition metal potassium-graphite lamellar compounds for the synthesis of ammonia from the elements and the catalysis of the equilibration by isotope exchange of the isotopic nitrogen molecules are shown to correlate. Connections between the state of metal in the catalyst exist with iron as metal which is shown by Mössbauer spectroscopy and the catalytic activity in relation to the potassium content.
    Notes: Die katalytische Aktivität von Übergangsmetall-Kalium-Graphitverbindungen bei der Synthese von Ammoniak aus den Elementen und bei der Einstellung des Isotopenaustauschgleichgewichts der isotopen Stickstoffmolekeln korrelieren miteinander. Im Falle von Eisen als Metall sind Beziehungen zwischen dem durch Mößbauer-Spektroskopie ermittelten Zustand des Metalls im Katalysator und der katalytischen Aktivität in Abhängigkeit vom Kaliumgehalt erkennbar.
    Additional Material: 3 Ill.
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  • 3
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Increase in the Reactivity of Apatitic Phosphates due to Mechanical ActivationThe lattice of natural apatitic phosphates was severely distorted by mechanical activation. At a high energy concentration in a centrifugal mill the crystals reach the X-ray amorphous state. The structural changes are investigated by infrared and X-ray methods. At increased degrees of activation the mechanically activated apatitic phosphates show enhanced solubility as a result of structural changes.
    Notes: Natürliche apatitische Phosphate werden durch mechanische Aktivierung in ihrer Gitterstruktur stark gestört, bei hohen Energiekonzentrationen in der Planetenmühle bis zum röntgenamorphen Zustand. Die auftretenden strukturellen Änderungen werden mit röntgenographischen und infrarotspektroskopischen Methoden untersucht. Die mechanisch aktivierten apatitischen Phosphate zeigen mit steigendem Aktivierungsgrad eine zunehmende Löslichkeit als Folge der strukturellen Änderungen.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 1689-1702 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Alcohol yields of 6.5% were obtained with Saccharomyces cerevisiae in lactasehydrolyzed acid whey permeate containing 30-35% total solids. Maximum alcohol yields obtained with Kluyveromyces fragilis were 4.5% in lactase-hydrolyzed acid whey permeate at a solids concentration of 20% and 3.7% in normal permeate at a solids concentration of 10%. Saccharomyces cerevisiae efficiently converted the glucose present in lactase-hydrolyzed whey permeates containing 5-30% total solids (2-13% glucose) to alcohol. However, the galactose, which comprised about half the available carbohydrate in lactase-hydrolyzed whey, was not utilized by S. cerevisiae, so that even though alcohol yields were higher when this organism was used, the process was wasteful in that a substantial proportion of the substrate was not fermented. For the process to become commercially feasible, an efficient means of rapidly converting both the galactose and glucose to alcohol must be found.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 21 (1979), S. 907-908 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 18 (1976), S. 1537-1555 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The response of a polarographic oxygen electrode to a step change and to an exponential change in bulk oxygen concentration was studied theoretically and experimentally for the case where there is a significant liquid film resistance at the outer side of the membrane-covered electrode. The probe response has been described by a mathematical model which takes into account the oxygen mass transfer through the liquid film and through the membrane. It is shown that substantial error could be introduced by neglecting the liquid film resistance. A test procedure is suggested to evaluate the error significance.
    Additional Material: 11 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 1019-1035 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ethanol production by Kluyveromyces fragilis and Saccharomyces cerevisiae was studied using cottage cheese whey in which 80 to 90% of the lactose present had been prehydrolyzed to glucose and galactose. Complete fermentation of the sugar by K. fragilis required 120 hr at 30°C in lactase-hydrolyzed whey compared to 72 hr in nonhydrolyzed whey. This effect was due to a diauxic fermentation pattern in lactase-hydrolyzed whey with glucose being fermented before galactose. Ethanol yields of about 2% were obtained in both types of whey when K. fragilis was the organism used for fermentation. Saccharomyces cerevisiae produced alcohol from glucose more rapidly than K. fragilis, but galactose was fermented only when S. cerevisiae was pregrown on galactose. Slightly lower alcohol yields were obtained with S. cerevisiae, owing to the presence of some lactose in the whey which was not fermented by this organism. Although prehydrolysis of lactose in whey and whey fractions is advantageous in that microbial species unable to ferment lactose may be utilized, diauxie and galactose utilization problems must be considered.
    Additional Material: 8 Ill.
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  • 8
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two types of bead-form macroporous carriers based on glycidyl methacrylate with ethylene dimethacrylate copolymers were used for the immobilization of penicillin amidase either directly or after chemical modificaton. Direct binding through oxirane groups, which is equally efficient at pH 4.2 and 7, is relatively slow and brings about an activity loss at low enzyme concentrations. The most efficient immobilization was achieved on glutaraldehyde-activated amino carier, irrespective of whether the amino groups were formed by ammonia or 1,6-diaminohexane treatment of the original oxirane carrier. Hydrazine treatment gave lower immobilization yields. The same is true of the azide method independent of the length of the spacer. Most enzyme activity was preserved by coupling the carbodiimide-activated enzyme to the carrier with alkyl or arylamino groups at the end of a longer substituent. Immobilization on diazo-modified carrier gave average results. Rapid immobilization by a lysine-modified phosgene-treated carrier resulted in an activity loss. It is suggested that multipoint and very tight attachment of the enzyme molecule to the matrix decreased the activity. The immobilized activity is quite stable in solution and very stable upon lyophilization with sucrose.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 983-1008 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The response of a polarographic oxygen electrode to a step change and to an exponential change in bulk oxygen concentration was studied theoretically and experimentally for the case where there is a significant liquid film resistance at the outerside of the membrane-covered electrode. The probe response has been described considering the start-up period of the concentration changes (the period of time that will elapse before the new concentration level is established and/or before the volumetric mass transfer coefficient kLa regains its steady-state value after the gas supply is opened to the fermentor). A linear change of the pertinent characteristics is assumed during this start-up period. It is shown that a substantial error could be introduced by neglecting the start-up period for cases frequently occurring in practice. In addition, the dependences of the probe response on the direct contact of bubbles with an electrode and on the fluid flow field around it were discussed.
    Additional Material: 14 Ill.
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  • 10
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thin Layer Chromatography of Chloro-Cyclophosphazenes. II. Separation of Chloro-Cyclophosphazenes (NPCl2)n (n=3-15)Thin layer chromatography on silica gel was used for separation of higher members of homologic series of Chloro-Cyclophosphazenes. Under the indicated conditions spots of 13 substances with help of new and selective detection reagents were located. The Rf values of the substance were mathematically worked up and the probable influences that enables the separation were discussed.
    Notes: Dünnschichtchromatographie auf Silicagel wurde zur Trennung der höheren Glieder der homologen Reihe von Chloro-Cyclophosphazenen benutzt. Unter den beschriebenen Arbeitsbedingungen wurden Flecke von 13 Stoffen mit neuen empfindlichen und selektiven Nachweisverfahren ermittelt. Die Rf-Werte wurden mathematisch bearbeitet, und die wahrscheinlichen Einflusse, die die Trennung ermöglichen, wurden diskutiert.
    Additional Material: 2 Ill.
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