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  • Wiley-Blackwell  (9)
  • Springer  (5)
  • 1975-1979  (14)
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  • 1
    Publication Date: 1978-01-01
    Print ISSN: 0372-820X
    Electronic ISSN: 1435-1536
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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  • 2
    Publication Date: 1978-01-01
    Print ISSN: 0372-820X
    Electronic ISSN: 1435-1536
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 256 (1978), S. 94-94 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 256 (1978), S. 93-94 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 11 (1979), S. 45-50 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Нейтрализация Н-морденита NaOH протекает по диффузионной кинетике, где ступенью, лимитирующей скорость процесса, является диффузия натриевых ионов в морденит. Кривые нейтрализации были определены с помощью ионообменной изотермы H3O+→Na+. С помощью раствора KF весь алюминий может быть экстрагирован из решетки цеолита NaY.
    Notes: Abstract Neutralization of H-mordenite with NaOH follows diffusion kinetics with the diffusion of sodium cations into the mordenite as rate-determining step; neutralization curves are determined by the H3O+→Na+ ion exchange isotherm. With KF solutions, all aluminium can be extracted from the lattice of NaY-zeolite.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 445 (1978), S. 65-72 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Oxide Catalysts. XXVII. Investigations on Zeolites CuNaY with Diffuse Reflectance SpectroscopyThe electronic spectra of CuNaY zeolite samples with different exchange degrees were interpreted in terms of crystal field theory. According to this model the Cu2+ cations are localized independent on exchange degree in three different coordination polyhedrons with symmetries of D4h, C4v, and C3v.With increasing temperature of dehydration (≥473 K) in the electronic spectra of the sample with 8 Cu2+/u. c. occur changes which are caused by formation of oxidic clusters.
    Notes: Die UV-VIS-Spektren von CuNaY-Zeolithen unterschiedlichen Austauschgrades werden im Rahmen der Kristallfeldtheorie interpretiert. Gemäß diesem Modell befinden sich die Kupferionen unabhängig vom Austauschgrad in drei verschiedenen Koordinationspolyedern mit D4h-, C4v- und C3v-Symmetrie.Mit steigender Dehydratisierungstemperatur (≥473 K) treten im Remissionsspektrum der Probe mit 8 Cu2+/EZ charakteristische Änderungen auf, die durch die Ausbildung von oxidischen Clustern hervorgerufen werden.
    Additional Material: 6 Ill.
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  • 7
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Oxide Catalysts. XXV. Catalytic Activity and Aging Properties of Modified Mordenites in the Cracking of n-OctaneMeH-mordenites (Me = Li, K, Mg, Ca, Ba) were prepared by ion exchange starting with H-mordenite (SiO2/Al2O3 mole ratio = 14). To characterize these samples the cracking of n-octane was used as catalytic test reaction. Surface OH groups and the adsorption of NH3 on these samples were investigated by i. r. spectroscopy. Unaffected by the kind of the exchanged cation the Brönsted acidity of the H-mordenite decreases monotonously with increasing content of the incorporated cation. The catalytic activity and (to a much higher degree) the rate of deactivation by coking during the reaction decrease as the Brönsted acidity decreases. The strong dependence of the Brönsted acidity on the deactivation rate points to a multi-site mechanism of the coking process.
    Notes: MeH-Mordenite (Me = Li, K, Mg, Ca, Ba) wurden ausgehend von einem H-Mordenit (Molverhältnis SiO2/Al2O3 = 14) durch Ionenaustausch hergestellt. Als Testreaktion zur Katalytischen Charakterisierung diente die n-Octanspaltung. IR-spektroskopisch wurden die OH-Oberflächengruppen und die Adsorption von NH3 an den Proben untersucht. Unabhängig von der Art des eingetauschten Kations sinkt die Brönsted-Acidität des H-Mordenits monoton mit steigendem Gehalt an den eingetauschten Kationen. Die katalytische Aktivität und (im weit Stärkeren Maße) die Desaktivierungsgeschwindigkeit (infolge „Verkokens“ während der Reaktion) sinken symbat mit der Brönsted-Acidität. Die starke Abhängigkeit der Geschwindigkeit der Desaktivierung von der Brönsted-Acidität weist auf einen Mehrzentrenmechanismus für die Verkokung hin.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Oxide Catalysts. XXII. Physico-chemical Characterization of CeNaY and CrNaY ZeolitesCeNaY and CrNaY zeolites with different degrees of exchange are characterized by DTA H2O adsorption, electron microscopy and UV-VIS spectroscopy.For CeNaY the thermal stability increases up to 45% exchange. There is no loss in crystallinity. CrNaY zeolitcs show minimal stabilities at 20-30% exchange. Above 48% exchange the crystallinity decreases.The optical spectra of hydrated CrNaY zeolites show that chromium is exchanged in the form of [Cr(H20)]3+ cations. Partially dehydrated zeolites exhibit a distorted octahedral and tetrahedral symmetry, resp., around the Cr3+ ions. In the highly dehydrated samples a part of Cr3+ ions is fixed in the hexagonal prism (octahedral environment of skeleton oxygen atoms).
    Notes: Es wird über einige Ergebnisse der Charakterisierung (DTA, H20-Adsorption, Elektronenmikroskopie, UV-VIS-Spektroskopie) von CeNaY- und CrNaY-Zeolithen unterschiedlicher Austauschgrade berichtet.Bei CeNaY-Zeolithen steigt die thermische Stabilität bis zu einem Austauschgrad von 45% an. Die Kristallinität bleibt erhalten. Die thermische Stabilität von CrNaY-Zeolithen geht bei Austauschgraden von 20-30% durch ein Minimum. Ab einem Austauschgrad von 48% sinkt die Kristallinität.Die optischen Spektren von hydratisierten CrNaY-Zeolithproben zeigen, daß das Chrom als [Cr(H20)6]3+-Kation eingetauscht wird. Für die partiell dehydratisierten Zeolithe erscheint eine verzerrte Oktaeder- bzw. Tetraedersymmetris um die Cr3+-Kationen. In den vollständig dehydratisierten Proben wird ein Teil der Cr3+-Ionen im hexagonalen Prisma in oktaedrischer Umgebung von Gittersauerstoffatomen fixiert.
    Additional Material: 6 Ill.
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  • 9
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Oxide Catalysts. XXIV. Adsorption and Catalytic Properties of CeNaY and CrNaY ZeolitesThe adsorption of benzene, n-butylamine and ammonia(isotherms and heats of adsorption) on CeNaY and CrNaY zeolites of different exchange degrees has been measured. The acidic properties were characterized by titration with n-butylamine. As function of exchange degree the adsorption and catalytic properties (cracking of cumene) both change in the same manner. Whereas the reaction rate constants up to exchange degrees of 40-50% change only insignificantly, they are exponentially increasing at higher exchange degrees. The energies of activation are nearly independent of the degree and run to 23-25 kcal mol-1.
    Notes: An CeNaY- und CrNaY-Zeolithproben mit unterschiedlichen Austauschgraden wird die Adsorption von Benzol, n-Butylamin und Ammoniak aus der Gasphase untersucht (Isothermen, Adsorptionswärmen). Die aciden Eigenschaften von CeNaY-Proben werden durch Titration mit n-Butylamin ermittelt. Mit dem Kationenaustauschgrad ändern sich die Adsorptions-und katalytischen Eigenschaften (Cumolcrackung) gleichsinnig. Während die Reaktionsgeschwindigkeitskonstanten sich bis zu Kationenaustauschgraden von 40-50% in beiden Reihen nur geringfügig ändern, steigen sie bei höheren Austauschgraden exponentiell an. Die Aktivierungsenergien sind nahezu unabhängig vom Austauschgrad und liegen zwischen 23 und 25 kcal mol-1.
    Additional Material: 4 Ill.
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  • 10
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Oxide Catalysts. XXVIII. Influence of Pretreatment on Catalytic Properties of Zeolites NiNaY and NiCoNaYThe influence of the pretreatment conditions on the acidic properties, the reduction degree of nickel, and the catalytic activity and selectivity of zeolites NiNaY and NiCoNaY in the alkylation of benzene with ethylene has been investigated.From the experimental results can be concluded that sec. buthylbenzene from benzene and ethylene is only formed on zeolite samples which contain both together BRÖNSTED acidic centres and Ni2+ cations or NiO. Catalysts which contain only metallic nickel are inactive for this reaction. Catalysts with nickel in different forms are active in the formation of ethylbenzene, diethylbenzene, butane and sec. buthylbenzene, the yields depending on the relation of Ni°, Ni2+, and NiO. Changing this relation makes possible to regulate the selectivity in the alkylation of benzene with ethylene.
    Notes: An NiNaY- und NiCoNaY-Zeolithproben wird der Einfluß der Aktivierungsbedingungen auf die aciden Eigenschaften, den Reduktionsgrad des sowie die katalytische Aktivität und Selektivität bei der Alkylierung des Benzols mit Äthylen untersucht.Die Ergebnisse führen zu dem Schluß, daß sec. Butylbenzol aus Benzol und Äthylen nur an den Zeolithproben gebildet wird, die neben Brönsted-sauren Zentren Ni2+ -Kationen oder eine NiO-Phase enthalten. Katalysatoren, die alles Nickel in Form von Metall enthalten, sind für diese Reaktion inaktiv. An Proben, die das Nickel in verschiedener Form enthalten, bilden sich Äthybenzol, Diäthylbenzol, Butene und sec. Butylbenzol, und ihre Ausbeuten hängen vom Ni°/Ni2+/NiO-Verhältnis ab. Mit der Veränderung dieser Größe kann man die Selektivität bei der Alkylierung von Benzol mit Äthylen regulieren.
    Additional Material: 3 Tab.
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