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  • Articles  (137)
  • Chemical Engineering  (137)
  • Physical Chemistry
  • 1975-1979  (79)
  • 1960-1964  (58)
  • Process Engineering, Biotechnology, Nutrition Technology  (137)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 885-890 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 1156-1156 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 354-357 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 1090-1096 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The presence of internal circulation in forming liquid drops has a significant effect on mass transfer rates. For the systems studied, no circulation was observed below a Reynolds number of 9.7. For Reynolds numbers between 9.7 and 34.4, transition from zero circulation to complete circulation during the entire drop formation period occurred. In studies on the rate of mass transfer from fixed volume drops with forced internal circulation, increases in mass transfer rates were found at Reynolds numbers which corresponded to those observed for the development of internal circulation patterns within the drop.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 139-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of type-304 stainless steel in a forced-convection closed-loop lithium system was investigated over a wide range of temperatures and velocities. Fundamental information concerning the mechanism for mass transport has been obtained by examining solution and deposition effects along flat plates. The rate-determining process for solution is transport from the solid to the interface, whereas deposition rates are liquid-phase controlled.Liquid-phase mass transfer coefficients were correlated with a maximum deviation of approximately 15% by the use of von Kàrmàn's analysis of the turbulent boundary layer along a flat plate, combined with the Chilton-Colburn empirical modification of the Schmidt group. In contrast no adequate model is available for the prediction of solution rate constants which must be determined experimentally. Mean values of the solution rate constants ranged from 0.154 to 0.750 × 10-5 cm./sec. at temperatures from 510° to 612°C. These values are on the order of 103 smaller than corresponding liquid-phase mass transfer coefficients.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 428-430 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 478-481 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rate studies were carried out for the ortho-para hydrogen conversion at liquid nitrogen temperature with a multiple-impregnation nickel on aluminum oxide catalyst. Data were obtained at pressures up to 400 lb./sq. in. gauge over a range of flow rates for three catalysts of different pellet sizes.For the largest particle, ⅛-in. cylinders, diffusion resistances were significant. Effectiveness factors were evaluated and found to be somewhat less that 0.5 for this relatively active catalyst. After the diffusion resistances were accounted for, the surface rate was correlated on the basis of a mechanism supposing molecular hyddrogen to be adsorbed on the surface. Separate evaluation of the catalyst for the hydrogen-deuterium exchange reaction suggested that dissociation was not significant at liquid nitrogen temperature.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 367-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite-difference method is presented for solving three-dimensional transient heat conduction problems. The method is a modification of the method of Douglas and Rachford which achieves the higher-order accuracy of a Crank-Nicholson formulation while preserving the advantages of the Douglas-Rachford method: unconditional stability and simplicity of solving the equations at each time level. Although the method has not yet been applied, the analysis in this paper suggests that it will prove to be the most efficient method yet proposed for the numerical integration of three-dimensional transient heat conduction problems.
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 437-441 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the effect of fixed packing on the properties of a gas-fluidized bed, including minimum fluidization velocity, pressure drop, and bed expansion. Experiments using a range of glass beads as fluidizing solid with smooth uniform spheres as packing indicate that both packing size and the ratio of particle to packing diameter are the main variables in correlating the results. Other solids of varying density and shape have also been used. In addition to smooth spherical packing, rough spheres and variously shaped packings such as Raschig rings, Berl saddles, and a cylindrical, open-ended screen packing have received preliminary study. With the screen packing, which occupies only 5% of the column volume, it has been possible to operate a fluidized bed at a much higher gas throughput without slugging than is possible with a conventional bed.A preliminary study has also been made of heat transfer rates, and the results indicate that the same factors are significant. With spherical packing, values of h of the order of 70% of that in a conventional bed have been obtained, while with screen packing values ranging up to 100% or greater have been observed.Possible applications of this technique and its limitations are also discussed.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 157-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A corresponding states method has been developed to predict the binary parameter in the unsymmetric-convention one-term Margules relation for binary activity coefficients of H2 and CH4 in solvents. In addition to the solvent density, only characteristic volumes used previously for partial molar volumes at infinite dilution and pure solvent compressibility are required. Comparisons with experiment for nonpolar solvents indicate that use of the method is usually significantly more accurate than assuming ideal solution (Henry's law).
    Additional Material: 2 Tab.
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