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  • Inorganic Chemistry  (5)
  • 1975-1979  (4)
  • 1965-1969  (1)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Neue —OSeF5- und —OTeF5-Verbindungen (1977)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 110 (1977), S. 1470-1476 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Derivatives of the —OSeF5 and —OTeF5 GroupsThe compounds O2N—OSeF5, OPF2—OSeF5, As(OSeF5)3, and Sb(OTeF5)3 are described and their structures are discussed. By fluorination of As(OTeF5)3 the new oxide fluoride of tellurium, trans-F2Te(OTeF5)4, was obtained.
    Notes: Die Verbindungen O2N—OSeF5, OPF2—OSeF5, As(OSeF5)3 und Sb(OTeF5)3 werden beschrieben und ihre Struktur erläutert. Ausgehend vom As(OTeF5)3 gelang durch Fluorierung die Herstellung eines neuen wohldefinierten Oxidfluorids des Tellurs: trans-F2Te(OTeF5)4.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19771100429
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  • 2
    Electronic Resource
    Electronic Resource
    Über Darstellung und Eigenschaften des Tetrakis-trimethyl-silyl-hydrazins und anderer silylsubstituierter Hydrazine (1969)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 102 (1969), S. 1247-1252 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung und Eigenschaften von N-Lithium-tris-trimethylsilyl-hydrazid, Tetrakis-trimethyl-silyl-hydrazin, N-Trimethylsilyl-N′-methyl-N′-phenyl-hydrazin und N.N-Bis-trimethylsilyl-N′-methyl-N′-phenyl-hydrazin werden beschrieben.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19691020416
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  • 3
    Electronic Resource
    Electronic Resource
    Übergangsmetall-pentafluoroorthochalcogenate (1975)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 108 (1975), S. 1823-1829 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal PentafluoroorthochalcogenatesPreparation and properties of some transition metal pentafluoroorthoselenates and -tellurates (1-4) are described. The transition metals always have their highest valency state: TiIV, VV, CrVI, WVi. For the first time a molecule containing five pentafluoroorthochalcogene groups attached to a central atom was made: WCl(OTeF5)5.
    Notes: Darstellung und Eigenschaften einiger Übergangsmetall-pentafluoroorthoselenate und -tellurate (1-4) werden beschrieben. Die Übergangsmetalle liegen stets in den höchsten Wertigkeiten vor: TiIV, VV, CrVI, WVI. Erstmals gelingt die Einführung von fünf Pentafluoroorthochalcogen-Gruppen an ein Zentralatom in der Verbindung WCl(OTeF5)5.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19751080606
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  • 4
    Electronic Resource
    Electronic Resource
    Kovalente Uranverbindungen des Typs FxU(OTeF5)6-x (1976)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 109 (1976), S. 1046-1052 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Covalent Compounds of Uranium of the Type FxU(OTe5)6-xPure U(OTeF5)6 is prepared. It is volatile in spite of the molecular weight of 1669 mass units and seems to be the inorganic nonpolymeric molecule with the highest molecular weight known. all compounds FxU(OTeF5)6-x have been detected by the n.m. r. method.
    Notes: Reines U(OTeF5)6 wurde dargestellt und ist leicht flüchtig, trotz der meines Wissens höchsten Molmasse (1669) für eine anorganisch nichtpolymere Verbindung. Darüber hinaus wurden alle Verbindungen der allgemeinen Formel FxU(OTeF5)6-x nachgewiesen.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19761090325
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  • 5
    Electronic Resource
    Electronic Resource
    Methylschwefelpentafluorid und einige seiner Derivate (1979)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 112 (1979), S. 1140-1146 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Methylsulfurpentafluoride and Some of its DerivativesMethylsulfurpentafluoride (5) was systematically synthesized, starting with SF5Cl and ketene. It is stable at room temperature against HF elimination. The reaction of SF5Cl and diketene gives compounds of the type SF5—CH2—X, but the title compound is not produced in this way.
    Notes: Methylschwefelpentafluorid (5) wurde systematisch synthetisiert, ausgehend von SF5Cl und Keten. Es ist bei Raumtemperatur stabil gegen HF-Eliminierung. Die Reaktion von SF5Cl und Diketen führt zu einer Vielzahl anderer Verbindungen des Typs SF5—CH2—X, in einfacher Weise jedoch nicht zur Titelverbindung.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19791120409
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