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  • Artikel  (16)
  • Polymer and Materials Science  (15)
  • idempotent  (1)
  • AERODYNAMICS
  • FLUID MECHANICS
  • 1975-1979  (10)
  • 1965-1969  (6)
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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1973-1985 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Comparisons were made of differential scanning-calorimetric (DSC) thermograms of both liquid and powdered commercial phenol-formaldehyde resins. By a combination of the results from analyses under a variety of conditions, such as ambient pressure, high pressure, using freeze-dried samples, and also by direct observation of the resin-curing process in wood-veneer assemblies, the curing reactions of phenol-formaldehyde resins were found to differ for resol and novolac systems. At a heating rate of 10°C/min, the resol resin showed endothermic curing reactions at temperatures of about 150°C, while the novolac-type resin showed an exothermic peak maximum at about 160°C. Results are presented to show how DSC can be used to differentiate between a resol and novolac system.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Periodica mathematica Hungarica 7 (1976), S. 137-139 
    ISSN: 1588-2829
    Schlagwort(e): Primary 22A15 ; Secondary 22A20 ; Topological semigroup ; boundary ; relative ideal ; radical ; idempotent ; topological group
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 2325-2332 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Poly(α,α,α′,α′-tetrafluoro-p-xylylene) was prepared by the pyrolysis of cyclo-di-(α,α,α′,α′-tetrafluoro-p-xylylene) and by the pyrolysis of α,α′-bis(alkylsulfonyl)-α,α,α′,α′-tetrafluoro-p-xylene. The pyrolysis of α,α′-dibromo-α,α,α′,α′-tetrafluoro-p-xylylene also gave the polymer, but the method is less satisfactory. Poly(α,α,α′,α′-tetrafluoro-p-xylylene) shows remarkable thermal and oxidative stability at elevated temperatures. Useful mechanical and electrical properties are retained after aging for 3000 hr at 250° in air. After initial change due to crystallization, tensile strength remains near 10,000 psi, elongation above 5%, and dielectric constants and dissipation factors at approximately 2.4 and .001, respectively.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 1545-1553 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Vinyl esters of some undecylenic acid derivatives and acrylates and methacrylates of undecyl and undecylenyl alcohols, which may be considered as derivaties of castor oil, have been polymerized and copolymerized with vinyl chloride to provide a variety of new polymers. The acrylate and the methacrylate of undecylenyl alcohol have been epoxidized to yield two new polymerizable monomers of potential usefulness as crosslinking agents in finished copolymers.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1189-1201 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The effect of water vapor on a polyimide has been investigated in the temperature region of -190 to 325°C using an automated torsion pendulum. A damping peak, TH2O developes at -122°C (1 Hz) in the thermomechanical spectra of the polymer which is due to water-polymer interactions. The peak intensifies as the humidity of the conditioning atmosphere, at both 30° and at 325°C, increases and attains a limiting value at about 3000 ppmv H2O. The process is reversible. It is concluded that the number of sites in the polymer for interaction with water is low and limited (〈0.3 molecule H2O per polymer repeat unit) and, assuming direct proportionality between the intensity of the loss peak and the amount of water adsorbed, that the adsorption of water vapor follows the Langmuir isotherm.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 1619-1626 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A dual-calibration method for the determination of molecular weights and molecular weight distribution of styrene-maleic anhydride copolymers (S/MA) by gel permeation chromatography (GPC) is introduced. It might be applicable to copolymers of other type. A linear relationship of intrinsic viscosity [η] and weight-average molecular weight (M̄w) for unfractionated S/MA in tetrahydrofuran (THF) at 25°C can be expressed by the equation \documentclass{article}\pagestyle{empty}\begin{document}$ \left[ \eta \right] = 3.98 \times 10^{ - 4} \bar M_w^{0.596} . $\end{document} The maleic anhydride content of the copolymers ranges from 5 to 50 mole-%, and the M̄w range is from 2 × 104 to 7 × 106. The plot of log [η] M̄w versus GPC elution volume of the S/MA copolymers falls on the same curve as that of the polystyrene standards in THF.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 967-970 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Relations are derived for the linear and volumetric thermal expansion coefficients of a filled polymer containing aligned ellipsoidal inclusions at finite concentrations. The analysis follows a procedure recently developed for elastic moduli by application of a generalized approach of Eshelby. The well-known Kerner equation is shown to be a limiting case of the present finding. From data on glass in epoxy resin, we conclude that the volumetric expansion varies only slightly with the aspect ratio of an ellipsoid; however, the longitudinal and transverse, linear, expansions show a strong dependence on the particle shape.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1305-1310 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Very few analyses exist for determining the adhesion f thin brittle films in the micron range on low modulus polymeric substrates. A theoretical model and experimental means are developed to determine the adhesion for this situation using the concept of fracture mechanics and Griffith's energy criterion. An expression for the adhesion is derived in terms of the external loading, material constants, and thicknesses of the films.The model is compared with measurements of brittle films vacuum deposited onto polymeric substrates. Excellent agreement is obtained and interfacial energies are calculated. Since the moduli of thin films are very difficult to determine accurately, the effect of a variation in measurements of this material parameter on the adhesion is calculated. The effect of varying preparative conditions is also discussed.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1311-1316 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Solvent coating is an important commercial technique utilized in fabricating thin films. In certain cases, undesirable strains may be built into the composite as the solvent is removed. The stress field in a two-layer sample and its distribution along the interface have been analyzed. By considering the shrinkage of the solvent cast film equivalent to applying an axial compressive load, interfacial expressions were derived which are valid for solvent drying of solution cast films. Experimental procedures and measurements are presented for the solvent casting of thin brittle films onto flexible polymeric substrates. Interfacial strains are determined and their dependence on accurate material property measurements is evaluated. The relation between the bulk and interfacial strain is illustrated.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 959-965 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The elegant approach of Eshelby, developed for dilute dispersions, is generalized to include the interaction of filler with filler. It is then utilized to determine the five elastic moduli of filled polymer containing aligned ellipsoidal particles at finite concentrations ϕ. The anisotropic particle shape is characterized by an aspect ratio ρ of an ellipsoid. The present theory compares well with available experiments in the literature. The experimentally verified Kerner equation for spherical particles and rule of mixtures for the longitudinal Young's modulus at ρ → ∞ are special cases of our new results.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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