ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Structure Determination of Boron Nitrogen Compounds, VI. The Crystal and Molecular Structure of Dichloro(diphenylamino)boraneDichloro(diphenylamino)borane crystallizes in the monoclinic space group P21 with a = 13.84, b = 7.77, c = 5.86 Å, β = 102.45° and two molecules per unit cell. The molecule was found to have a nearly planar Cl2BNC2-skeleton, whereas the phenyl groups are strongly tilted out of this plane. The B—N distance of 1.380 Å suggests that the boron and nitrogen atoms are linked by a double bond.
Notes:
Dichlor(diphenylamino)boran kristallisiert in der monoklinen Raumgruppe P21 mit a = 13.84, b = 7.77, c = 5.86 Å, β = 102.45° und 2 Molekülen in der Elementarzelle. Das Molekül zeigt ein nahezu planares Cl2BNC2-Gerüst, während die Phenylgruppen sehr stark aus dieser Ebene herausgedreht sind. Der B—N-Abstand mit 1.380 Å läßt auf eine Bor-Stickstoff-Doppelbindung schließen.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19751080714
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