ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions By the action of secondary amines, and depending on their nature, perfluoro-4-methyl-2-pentene either forms substitution products of the “ally” fluorine atom, or isomerizes into perfluoro-2-methyl-2-pentene and perfluoro-2-methyI-1-pentene, which form products of the substitution of the “vinyl” fluorine atom. As a result, 4-dlalkylaminoperfluoro-2-methyl-2-pentene, 2,3-dialkylaminoperfluoro-2-methyl-2-pentene, and 1-dialkylaminoperfluoro-2-methyl-1-pentene are obtained. The relative amount of the last compound increases in the series of the amines used: pyrrolidine, piperidine, hexamethyleneimine, dimethylamine, diethylamine.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00954714
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