ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Optically active S-(+)- and R-(−)-N-vinyl-3-methyl-2-pyrrolidones are synthesized and radically polymerized using AIBN as the initiator. The resulting high molecular weight polymers are optically active and soluble in a wide variety of solvents including water. IR and 13CNMR spectra are reported and agree with a polyvinylic enchainment of the repeating units. The ORD and CD spectra of (+)poly-N-vinyl-3-methyl-2-pyrrolidone in methanol are described.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00254357
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