ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A new method of differentiating between the different mechanisms operative for 13C solvent effects is proposed. This approach, in which the 13C solvent shifts of C-1 of tert-butylcyclohexane are selected for the reference solvent shifts, allows the study of 13C solvent shifts measured from an internal TMS reference. Using this method, the solute factor related to the van der Waals contribution can be estimated, and specific solvent effects other than the van der Waals effect can also be detected.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270180303
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