ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1980-1984  (1)
Collection
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    The oxidation of Co2(CO)8, Mn2(CO)10 and Fe(CO)5 by dibenzoyl peroxide. Kinetics and mechanism (1984)
    Springer
    Transition metal chemistry 9 (1984), S. 265-267 
    Details
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Dicobalt octacarbonyl in toluene solution can be quantitatively oxidized at room temperature with dibenzoyl peroxide to cobalt(II) benzoate and carbon monoxide. The rate of CO evolution is first order in dicobalt octacarbonyl, first order in dibenzoyl peroxide, and negative first order in CO. Similar behaviour leading to manganese(II) benzoate is observed with dimanganese decacarbonyl. Sixteen electron rather than seventeen electron intermediates are involved in these reactions. In contrast to the dinuclear carbonyls, Fe(CO)5 is oxidized by dibenzoyl peroxide in an autocatalytic reaction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00624470
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...