ISSN:
1572-8986
Keywords:
Energy transfer
;
helium
;
cadmium
;
gaseous plasma
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Technology
Notes:
Abstract Light absorption and emission spectroscopy were used in studies of the time dependences of the CdII spectral emission and Hem(23S) number density in the stationary afterglow of helium-cadmium mixtures. Transitions from 12 CdII energy levels were monitored in the afterglow. The five CdII states below 20 eV are produced, either directly or via cascading, by the Penning ionization of Cd by Hem(23S). The remaining CdII states studied are produced by the chargeexchange excitation of Cd by He+. No evidence was found for the production of CdII energy levels by charge transfer between Cd and He 2 + or by Penning ionization of Cd by He 2 m (23σ u + ). A value of (5.4±0.3)×10−10 cm3 sec−1 was measured for the reaction rate coefficient for the Penning ionization of Cd by Hem(23S), and a value of (2.1±0.2)×10−10 cm3 sec−1 was measured for the reaction rate coefficient for charge exchange between He+ and Cd at a gas temperature of 200°C.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00566375
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