ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1,2endo-Trimethylenenorbornane (1) in the presence of aluminium bromide in carbon disulfide at -60° isomerizes at a much higher rate than its 2exo-isomer 2 to 2endo, 6endo-trimethylenenorbornane (3) as the sole product. By consequence, the hydrocarbon 2 being the next intermediate in the sequence of the adamantane rearrangement of 1 seems to be very unlikely.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19800630520
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