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  • 1980-1984  (2)
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  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Blends of poly(vinyl butyral) (PVB) and of a copolymer of bisphenol A and epichlorohydrin (Phenoxy) with poly(N-vinyl-2-pyrrolidone) (PVP) were prepared by solution casting. The glass transition temperatures Tg for different compositions of the blends were measured by differential scanning calorimetry (DSC). The Tg behaviour of PVB/PVP blends suggests the existence of a single phase for blends containing less than 50 wt.-% PVP, and of two phases in blends containing more than 50 wt.-% PVP. Phenoxy/PVP blends showed to be miscible over the entire composition range. It was found that the Gordon-Taylor equation predicts adequately the Tg-composition dependence with a K parameter equal to 0,5 and 1,25 for PVB/PVP and Phenoxy/PVP blends, respectively.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 184 (1983), S. 1741-1747 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Blends of the polycarbonate of bisphenol-A (PC) with polyacrylate (PA), an aromatic polyester formed from bisphenol A and terephthalic acid/isophthalic acid, were prepared by both melt and solution casting, and their transitional behaviour was examined by differential scanning calorimetry (DSC) and thermo-optical analysis (TOA). Each blend composition was found to have a single glass transition temperature by DSC and by TOA. This result suggests that polycaronate and polyarylate form blends containing a single amorphous phase. Ester-carbonate interchange reactions during melt-mixing were experimentally found to be unimportant. Melting point depression was used to estimate the blend interaction parameter χ12.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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