ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Polymerizations of methyl methacrylate and styrene have been performed in the presence of thecis andtrans isomers of 4-methoxy-4′-chlorostilbene (SSTL) using as initiators benzoyl peroxide and 2-cyano-2-propylazoformamide, both enriched with carbon-13.13C-NMR spectra of the polymers show that SSTL units are present at many of the sites adjacent to benzoate end-groups but not to a detectable extent at sites adjacent to 2-cyano-2-propyl end-groups. The presence of the substituents in the molecule of stilbene greatly enhances its reactivity towards the benzoyloxy radical.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00958659
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