ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The preparation and characterization of a series of new coordination compounds of cobalt(II), nickel(II) and palladium(II) containing 2-picolyl- or 2-lutidyl-methyl ketone (HPMK or HLMK) and various anions, Cl−, Br−, NO 3 − , NCS− or BF 4 − , are reported. Complexes of square planar, tetrahedral and octahedral stereochemistry as well as five-coordinate species were isolated. The reaction products were found to be dependent on the molar ratios, pH and the temperature at which the reaction takes place. Cobalt(II) thiocyanate was found to form a complex of the type [CoL3][Co(NCS)4] (L = HPMK or HLMK). Also complexes containing coordinated BF4 were isolated. The ligand field parameters (Dq, B′ and β) for the cobalt(II) and nickel(II) complexes were calculated using the averaged-ligand-field approximation. The influence of the substituents of theses parameters and on the stereochemistry are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00620722
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