ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Pseudohalide complexes of the (η-cpL)TiXZ type (where cp = cyclopentadienyl, L = η-McCs5-H4 and X = N3, NCS, NCO or NCSe) have been prepared in aqueous and nonaqueous media and characterized by elemental analyses, i.r. and n.m.r. spectroscopy. I.r. spectroscopy shows that NCS, NCO and NCSe are bonded to the titanium atom through nitrogen in these complexes which are thus true isothiocyanato, isocyanato and isoselenocyanato derivatives respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01396867
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