ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
2-Arylazo-5-dimethylaminobenzyl alcohols (1) were prepared and used for the preparation of 2-arylazo-5-dimethylaminobenzyl acrylates (2) and methacrylates (3); these compounds were characterized by melting points, IR and 1H NMR spectra. The coloured compounds 2 and 3 were subjected to radical homopolymerization in solution initiated with AIBN at 70°C, and [η], IR and 1H NMR spectra of the polymers were determined. Alternatively, the coloured polymer with 2-(2-chlorophenylazo)-5-dimethylaminobenzyl methacrylate monomeric units was prepared by coupling of the copolymer of 3-dimethylaminobenzyl methacrylate and styrene with 1-chlorobenzenediazonium chloride.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1981.021820705
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