ISSN:
0098-1273
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The results of measurements of the optical absorption spectra, IR absorption spectra, thermogravimetric analysis, and elementary analysis of pyrolyzed polyacrilonitrile are presented as a function of the pyrolysis temperature Tp and of the duration of pyrolysis. At Tp ∼ 200°C, an intermediate phase was discovered, containing conjugated CN sequences and a completely unreacted carbon backbone. The optical absorption data imply that the resulting polymer is a semiconductor with a delocalized π-electron system and an energy gap Eg ⋍ 2.5 eV. For Tp 〉 260°C, the weight loss rapidly increases, and the absorption edge gradually broadens and shifts to lower energies. The resulting polymer (after higher-temperature pyrolysis) contains CN and C=C—C conjugation sequences, but appears to be a complex structure consisting of a mixture of different chemical species.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1984.180220708
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