ISSN:
0570-0833
Keywords:
Multiple bonds
;
Bond theory
;
Nitrido ligand
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Numerous nitrido complexes of transition metals show very short metal-nitrogen bond lengths, suggesting M≡N-triple bonds. At present, compounds of this type are being intensively investigated. In particular the molybdenum complexes are considered as model substances for the study of at least an intermediate step of N2-assimilation. This article contains a review of the structure and bonding, as well as syntheses and reactions of these complexes.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.198104133
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