ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Complex Catalysis. XV. Cationic η3-Allyl-bis(triorganylphosphite)nickel(II) Complexes as Catalysts for the Stereoregular Butadiene PolymerisationSynthesis and catalytic properties of [C3H5NiL2]PF6 complexes 1a-f with L = tri-ethyl-, -isopropyl-, -phenyl-, -o-tolyl-, -thymyl- and o-biphenylylphosphite are described. It is shown how electronic and steric effects of the phosphite ligands in these complexes control their catalytic activity and selectivity in 1,4-polymerization of butadiene.
Additional Material:
7 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19843260102
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