ISSN:
1600-5767
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Geosciences
,
Physics
Notes:
Crystal data are reported for six derivatives of 1,2-O-isopropylidene-3-C-(pyridin-2-yl)-β-D-psicopyranose, C14H19NO6, previously studied in solution by NMR spectroscopy. Molecules that differ only by the replacement of H by CH3 on one non-ring oxygen atom, converting an alcohol to an ether molecule, show no similarity in cell dimensions, and have different numbers of molecules per cell. All six phases belong to non-centrosymmetric space groups, four to P212121 and two to P21; in agreement with previously reported optical activity of these molecules in solution, it is concluded that only molecules of one-and-the-same handedness are present in any one of the crystalline phases.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0021889881009850
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