ISSN:
1573-9686
Source:
Springer Online Journal Archives 1860-2000
Topics:
Medicine
,
Technology
Notes:
Abstract Three diamine-extended polyether urethanes were prepared and their photodegradation studied. We find that the structure of the urea, as well as the urethane linkage, is important in determining photodegradation and discoloration of the polymers. Both processes can be minimized by using aliphatic diisocyanates and aliphatic diamine chain-extenders that contain no activated hydrogen alpha to nitrogen. In particular, an N-aryl urethane and an N-benzyl urea polymer photodegrade at about the same rate, but the N-aryl urethane that can form an extended conjugated system discolors more rapidly. The mechanisms for photodegradation of aryl and alkyl urea groups involving initial N-C bond cleavage appear to be analogous to the accepted mechanisms for the corresponding urethanes. After initiation, degradation of the polyether poly(oxypropylene glycol) also contributes to loss in molecular weight.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00000002
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