ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
1,3(N→N)-Migration of N-Heterosubstituted N,N′-DimethylbenzamidinesHeterosubstituents such as chlorine, diphenylsulfonio, triphenylphosphonio, and triphenyl-arsonio are shown to migrate between the nitrogen atoms in N,N′-dimethylbenzamidine. The tri-phenylstibonio group, however, prefers a 4-membered chelate complex with 6 ligands.
Notes:
Zwischen den beiden N-Atomen in N,N′-Dimethylbenzamidin wandern Heterosubstituenten wie Chlor, Diphenylsulfonio, Triphenylphosphonio und Triphenylarsonio mehr oder weniger schnell hin und her. Demgegenüber bevorzugt die Triphenylstibonio-Gruppe einen Vierring-Chelat-komplex mit sechs Liganden.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130418
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