ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Studies on the Autoxidation of cis- und trans-β-Methyl StyreneIn the autoxidation of cis- and trans-β-methyl styrene at temperatures between 80 and 120°C the C=C-double bond is preferably attacked: 35-60% of epoxides and their consecutive products and 25-50% of benzaldehyde are obtained. Products of allylic oxidation are formed only with yields lower than 1%; high-boiling or polymeric products, respectively, which could not be detected gaschromatographically are formed with yields lower than 20%. The ratio of cis- to trans-epoxides in the case of cis-β-methyl styrene oxidation amounts to about 0.04, in the case of trans-β-methyl styrene oxidation this ratio is about 0.01.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19803220302
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