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  • Articles  (117)
  • Springer  (105)
  • De Gruyter  (12)
  • 1980-1984  (114)
  • 1925-1929
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  • Articles  (117)
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  • 1
    ISSN: 1432-2234
    Keywords: Closed-shell INDO-CI method ; Trisdiimine iron(II) complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract An INDO-CI method in π-approximation extended for transition metal complexes with organic ligands is presented. The σ-polarization in the complex is estimated using a two-dimensional EHT calculation and considered in the π-calculation by means of the diagonal Fock matrix elements. The method is tested for four trisdiimine iron(II) complexes. In agreement with the experimental absorption spectra the calculations show that diimine complexes with non-heterocyclicly bound nitrogen atoms exhibit a large red-shift of the characteristic charge-transfer transition increasing the number of aromatic rings. Contrarily, for diimine complexes with heterocyclicly bound nitrogen atoms no shift of the charge-transfer transition was obtained.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of plant growth regulation 2 (1983), S. 19-29 
    ISSN: 1435-8107
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A new plant growth retardant, the norbornenodiazetine derivative 5-(4-chlorophenyl) - 3,4,5,9,10 - pentaaza - tetracyclo - 5,4,1,02.6,08.11- dodeca - 3,9 - diene (NDA) was tested for its effects on growth ofZea mays suspension cultures. It was shown that NDA could inhibit cell division almost completely at a concentration of 5× 10−5 M, while 80% of cells could be considered viable. Tracer experiments revealed that NDA inhibited thymidine, uridine, and leucine uptake into cells after 30 min of application. In contrast, amino acid incorporation into proteins was reduced only after one day of treatment and incorporation of precursors into DNA and RNA still later. Since NDA stimulated DNase, RNase, and protease activity in the cells simultaneously, an enhancement of DNA and RNA in cells possibly was prevented. That NDA affected protein synthesis indirectly seemed to be proved by the late point in time of its action on leucine incorporation and by only slight effects on cell free translation. An explanation of these findings could be an alteration in or inhibition of sterol biosynthesis caused by NDA, because it is known that sterols play an important role in controlling permeability of plant membranes as well as in maintaining normal protein synthesis. Thus we tested NDA for its effects on sterol production in maize cells and demonstrated that the composition of the sterol fraction, mainly stigmasterol and β-sitosterol, was clearly changed qualitatively as well as quantitatively.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 304 (1982), S. 293-299 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract New 0+-levels have been identified at 1,436 keV and 1,859 keV in98Zr through experiments at the fission product separators OSTIS and JOSEF. Half-lives of these levels of 0.69 ns and 0.24 ns, respectively, have been determined from measurements of delayedβ,γ coincidences.E0 transitions depopulating these 0+-levels have been observed. The results are in agreement with the assumption of shape coexistence in98Zr.
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  • 4
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Beta-delayed neutron emission from the precursors93–100Rb to excited states in the residual nuclei92–99Sr has been measured by means ofγ-ray and neutron spectroscopy. In general, considerable neutron feeding of excited final states is observed. The experimental branching ratios (P n i ) are compared to predictions from statistical model calculations. It is demonstrated that the main parameter affecting theP n i -values is the shape of theβ-strength function (S β). For several Rb isotopes hindrance, respectively enhancement of neutron branches to specific final states is observed giving evidence for the persistence of intermediate structure of the neutron-emitting states. By the example of98Rb it is shown that a few integralβ-delayed neutron properties may be sufficient to derive first estimates on the real shape ofS β above the neutron binding energy. This result is of importance for exotic nuclei where detailed spectroscopic investigations are precluded.
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  • 5
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An intrinsic Germanium detector of 10 mm depth and 300 mm2 sensitive area has been used to determineβ-endpoint energies for Rb, Sr and Y fission products. It was calibrated with monoenergetic electrons supplied by a magnetic conversion electron spectrometer for the energy range from 1.6 to 8 MeV. The energy calibration of the detector is linear with deviations less than 2 · 10−4, and the detector was recalibrated daily using precisely known gamma rays of90Rb. At the on-line fission product separator OSTIS at the ILL, Grenoble the endpoints ofβ-singles-spectra have been determined andQ-values deduced if possible also from beta-gamma coincidence measurements. The obtainedQ-values are:88Rb:(5 318±4) keV,89Rb: (4 510 ± 8) keV,90Rb: (6 578 ± 15) keV,91Rb: (5 857 ± 8) keV,91Sr: (2 704.5 ±3) keV,92Rb: (8 111 + 15) keV,93Rb:(7 485 ± 15) keV,94Rb: (10 304 ± 30) keV,94Sr: (3 512 ± 5) keV,94Y: (4 920 ±5)keV,95Rb: (8 947 ±100) keV,95Y: (4 445±5) keV,96Rb: (11 303±250) keV,96Sr: (5 413±20) keV,96Y: (7 120 ±50) keV,97Rb: (10 020 ±50) keV.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 305 (1982), S. 93-94 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Beta-delayed neutron measurements on95Rb have indicated evidence for two heretofore unknown excited O+ states in94Sr which are not fed by ß -decay from the Jπ = 3− ground state of94Rb.
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  • 7
    ISSN: 1434-6052
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Further experimental evidence is given for theF meson through its decay into η′s. Results are presented for the decay channels ηπ±, ηπ0π± and ηπ+π−π±, and confirm those obtained in a previous experiment.
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  • 8
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An intrinsic germanium detector was used to measure the beta endpoint energies of heavy fission products supplied by the on line mass separator OSTIS installed at the high flux reactor of the Institut Max von Laue-Paul Langevin, Grenoble. The endpoints of singles-spectra have been determined and, by means of beta-gamma coincidence measurements also most of theQ β-values of the following neutron-rich nuclides could be deduced with high accuracy:138Cs: (5388±25)keV,139Cs: (4213±5)keV,139Ba: (2336±25)keV,140Cs: (6220±15)keV,141Cs: (5252+15/-60)keV,141Ba: (3208±35)keV.142Cs: (7329±20)keV,143Cs: (6287+40/-250)keV,143Ba: (4259±40)keV,144Cs: (8451±30)keV,145Cs: (7358±70)keV.146Cs: (9300±900)keV,146Ba: (4280±100)keV.146La: (6175±100)keV. The results are compared with experimental results of direct mass measurements and some predictions by mass formulae.
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  • 9
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Nosiheptide (9671 R.P.) isolated fromStreptomyces actuosus 40037 (NRRL 2954) is a sulfur-containing polypeptidic antibiotic, quite different from all the other members of this family. Very active in vitro against gram-positive bacteria, it is inactive in vivo in experimentally infected mice. Not toxic, even at high dose, it may be used as a feed additive for chickens and pigs and it shows a favourable effect on the growth and conversion index.
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  • 10
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Der untere, ultramafische Teil des Chalkidiki Komplexes besteht aus einer wechselnden Abfolge von Chromititen, Duniten und Harzburgiten, die sich zyklisch wiederholt. Diese zyklische Abfolge ist in guter Übereinstimmung mit einer Entstehung als magmatische Kumulate. Das tektonische Gefüge, das auf die Kumulat-Texturen überprägt wurde, weist jedoch auf Deformationen in festem Zustand in beträchtlicher Tiefe hin. Die vorliegende Untersuchung befaßt sich mit dem Chemismus und den Texturen der Chromite. Besonderes Interesse wendet sich dabei den Wechselbeziehungen zwischen den Zusammensetzungen, der Art des Vorkommens und den assoziierten Silikaten zu. Dabei zeigt sich, daß die untersuchten Chromite in vieler Hinsicht Ähnlichkeiten sowohl mit podiformen wie mit stratiformen Vorkommen erkennen lassen. Geometrisch und texturell gesehen gehören sie dem podiformen Typ an. Nicht in Einklang damit stehen jedoch die beträchtlichen Eisengehalte sowie die deutlichen Wechselbeziehungen zwischen der Zusammensetzung von Chromit und der koexistierenden Silikate, und schließlich auch der kryptische Lagenbau, den die zwel Mineralgruppen erkennen lassen. Ein genetisches Modell wird vorgeschlagen, das fraktionierte Kristallisation einer ultrabasischen Schmelze von im wesentlichen gleichmäßiger Zusammensetzung vorsieht, die in periodischen Abständen der Magmenkammer zugeführt wurde. Eine Aufwölbung des oberen Mantels, die schrittweiser, partieller Aufschmelzung ausgesetzt ist, könnte diesen Bedingungen entsprechen.
    Notes: Summary The lower ultramafic part of the Chalkidiki Ophiolite Complex consists of a successive alternation of chromitite, dunite, and harzburgite, which is repeated periodically in a cyclic manner. This cyclic pattern is consistent with an origin as magmatic cumulates. However, the tectonic fabric superimposed on the cumulate texture of this sequence suggest a solid-state deformation at considerable depth. In the present study, the textural and chemical features of chromite are discussed. The interrelationships between the compositions of chromite, its mode of occurrence as well as the associated silicates are emphasized. It is found that the investigated chromites have properties in common with both podiforn and stratiform chromites. From a geometrical and structural point of view, they are of podiform type. On the other hand, their appreciably high iron content, the strong interdependence between the composition of chromite and the coexisting silicates together with the cryptic layering exhibited by the two mineral groups contrast markedly with podiform chromites. An alternative hypothesis is proposed involving fractional crystallization of an ultrabasic melt introduced to the magma chamber as periodic inflows of essentially the same composition. An upwelling upper-mantle that is subjected to stepwise partial fusion may fulfill these conditions.
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