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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 516 (1984), S. 30-34 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of BaHg(CN)4 · 4 PyridineThe structure of the tetragonal BaHg(CN)4 · 4 Pyridine (space group I4, a = 1119.4(7), c = 1 057.9(7) pm, Z = 2, dc = 1.87 g · cm-3) contains tetrahedral Hg(CN)4 and bisdisphenoide Ba(NC)4(py)4 groups, which are linked together by Hg—CN—Ba bridges. The BaHg(CN)4 framework consists of a 3-dimensional network of all round edge-sharing tetrahedrons. The analogous strontium compound is isotype with a = 1 108.2(9) and c = 1 035.3(14) pm.
    Notes: In der Struktur des tetragonalen BaHg(CN)4 · 4 Pyridin (Raumgruppe I4, a = 1119,4(7), c = 1 057,9(9) pm, Z = 2, dc = 1,87 g · cm-3) sind tetraedrische Hg(CN)4- und bisdisphenoide Ba(NC)4(py)4-Gruppen über Hg—CN—Ba-Brücken zu einem Raumnetz verknüpft. Dem BaHg(CN)4-Gerüst liegt ein Aufbau aus allseitig eckenverknüpften Tetraedern zugrunde. Die analoge Strontium-Verbindung ist isotyp mit a = 1 108,2(9) und c = 1 035,3(14) pm.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1131-1138 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rates of the MgCl2-catalyzed reaction between cellulose and 4,5-dihydroxy-1,3-bis(hydroxymethyl)-2-imidazolidinone were measured at 70, 90, and 110°C. The rate constants were determined by curing the resin for various times, extracting the unreacted resin, and determining its concentration by liquid chromatography. The energy of activation was calculated from the rate data. This work confirms the pseudo-first-order behavior of this reaction.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 3569-3577 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model N-methylol reactant system based on pyrrolidone derivatives has been used to study the chemical factors that control formaldehyde release. Fabric samples of known composition were prepared from chemically pure reactants and formaldehyde release was determined by the AATCC Sealed Jar Test. This work provides support for prior suggestions and a more direct approach for understanding unexpected results from tests on post-and precure fabrics. In addition, new findings demonstrate that the N-methylol reactant, its byproducts, and pure zinc nitrate are capable of reducing the level of formaldehyde release.
    Additional Material: 6 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 517-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 233 (1937), S. 151-154 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 233 (1937), S. 155-160 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 235 (1937), S. 77-82 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 3579-3585 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Residues remaining after drying and curing cotton fabric with either sodium bisulfate or zinc nitrate and N-methylolpyrrolidone, a monofunctional model durable press agent, have been quantitated by high performance liquid chromatography. The residues were identified as pyrrolidone, N-methylolpyrrolidone, N,N′-methylene-bis-2-pyrrolidone, and N,N′-(oxydimethylene)bis-2-pyrrolidone. The two catalysts fixed approximately the same amount of the N-methylolpyrrolidone to cellulose, but generated different ratios of the extractable residues. A comparison of the levels of these residues that are capable of releasing formaldehyde is given. The dominant residue from the NaHSO4 treatment was N-methylolpyrrolidone, while zinc nitrate generated more N,N′-(oxydimethylene)bis-2-pyrrolidone.
    Additional Material: 2 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 36-40 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Studies on the Hydrolysis of Aromatic SulfochloridesThe hydrolysis of aromatic sulfochlorides can bei described by a second-order law. Due to the strength of the base the constants of velocity are between 10-6 (H2O) or 103 (OH-) 1 mol -1 s-1 respectively. The reaction of benzensulfochlorides proceeds according to an addition-elimination mechanism, whereas benzylic sulfochlorides, reacting with a strong base, proceed to an elimination-addition mechanism.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 498 (1983), S. 75-84 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Novel High Pressure Modifications of Rare Earth Trichlorides in the RhF3-TypeThe results of high pressure investigations on Rare Earth trichlorides crystallizing with the AlCl3-type arrangement under normal conditions are reported. In addition to the PuBr3-type geometry, formed at higher pressures, a new structure type is found in a lower pressure range. This high pressure phase is isotypic with the RhF3-type arrangement, which so far has only been found with fluorides. It is packed more efficiently and shows a slightly higher primary coordination due to the higher symmetry of the coordination polyhedra compared with that of the original AlCl3-type structure. We present a model for the mechanism of transformation.
    Notes: Wir berichten über Hochdruckversuche an Seltenerd-Trichloriden, die unter Normalbedingungen im AlCl3-Typ kristallisieren. Zusätzlich zu dem bei höheren Drücken gefundenen PuBr3-Typ tritt in mittleren Druckbereichen eine neue Struktur auf, deren Isotypie zum RhF3-Typ durch eine Röntgenstrukturanalyse nachgewiesen werden konnte und die unter Normalbedingungen bislang nur bei Fluoriden beobachtet wurde. Sie stellt eine dichtere Packung dar und zeigt eine höhere Primärkoordination durch Symmetrisierung. Wir diskutieren ein Modell für den Verlauf der strukturellen Reorganisation.
    Additional Material: 2 Ill.
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