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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 481 (1981), S. 107-116 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Electrochemical Syntheses. VIII. Preparation of π-Cyclopentadienyl Metal CompoundsThe electrochemical synthesis of π-cyclopentadienyl metal compounds M(π-Cp)2 (M = Fe, Co, Ni) and of cyclopentadienyl carbonyl derivatives (π-Cp)nM(CO)m(M = Fe, Co, Ni, Ti, V) has been investigated. Most of the complexes can be prepared directly from the corresponding metal anodes, monomeric cyclopentadiene (and CO) in moderate or good yields.
    Notes: Die elektrochemische Synthese von π-Cyclopentadienylmetallverbindungen M(π-Cp)2 (M = Fe, Co, Ni) und von Cyclopentadienylcarbonyl-Derivaten des Typs (π-Cp)n-M(CO)m (M = Fe, Co, Ni, Ti, V) wurde näher untersucht. Die Mehrzahl der Komplexe läßt sich direkt aus den entsprechenden Metallanoden, monomerem Cyclopentadien (und CO) in mäßigen bis guten Ausbeuten darstellen.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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