ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Chemistry  (18)
  • Polymer and Materials Science  (9)
  • 61.46.+w
  • 1980-1984  (8)
  • 1965-1969  (11)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Isothermal calorimeter for studies of polymer solution processes (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 555-568 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A simple differential, isothermal calorimeter has been built to study the thermodynamics of interactions associated with a variety of polymer solution processes. The calorimeter is readily operated at temperatures ranging from ambient to about 200°C., temperature adjustments are rapid, and the apparatus is rugged enough to permit application to commercial process studies. Though less sensitive than microcalorimeters, it represents an attractive combination of satisfactory accuracy, speed, and flexibility of operation. The operation of the calorimeter is demonstrated by measurements of the heat of solution of sodium chloride in water and the heats of solution of various polyolefins in Tetralin and α-chloronaphthalene. The latter tend to confirm the presence of polymer aggregates in chloronaphthalene solutions below the thermodynamic melting temperature of the polymer.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050313
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Effect of carbon black on time dependence of the melt flow indexPaper presented at 22nd ANTEC Meeting, Society of Plastics Engineers, Montreal, Canada, March 1966. (1967)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 1043-1053 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Time dependence in the melt indexing of polyolefins stabilized against thermally induced changes is well known, the prevalent effect being an increase in melt index toward a steady-state value. The melt index of polyethylenes compounded with carbon black has been found to decrease, in some cases radically, although oxygen uptake data show no evidence of thermal instability. The melt index-time plot can be restored to its normal shape by adding excess quantities of a standard thioether antioxidant. Data are rationalized by assuming that polyethylene adsorbs on the available pigment surface, forming a crosslink network. The thioether antioxidant, however, may adsorb preferentially, thereby restoring the normal response of the polymer to forces resulting in its capillary extrusion. The results emphasize the contribution of chain orientation effects to the time dependence of melt index.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1967.070110704
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Surface characteristics of solvent-cast polymers (1980)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 1961-1968 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Films of poly(methyl methacrylate) (PMMA), polystyrene, and a styrene/acrylic terpolymer have been cast from solutions of varying thermodynamic quality and the film properties studied by inverse gas chromatography and by critical surface tension measurements. Surface properties of the non-polar polystyrene were independent of solvent medium, but significant variations in these properties were observed in the case of PMMA and the terpolymer. Solvent balance also appeared to affect the bulk properties of the latter films, as judged by the penetration rates of interacting liquids. The observations indicate the feasibility of controlling film properties of the solid by the appropriate selection of solution media; a time-dependent variation in solid properties is to be expected, however, as the film structure attains an equilibrium state.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1980.070250913
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Recent Progress in Microcalorimetry. Von E. Calvet und H. Prat, herausgeg. und aus d. Französ. übers. v. H. A. Skinner. Pergamon Press, Oxford-London-New York-Paris 1963. 1. Aufl., XII, 178 S., zahlr. Abb., geb. £ 3.0.0. (1965)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 77 (1965), S. 555-555 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19650771230
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Cause and effect in time dependent flow of thermoplastic melts - a review (1966)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 6 (1966), S. 317-323 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The factors leading to time dependnt variations of melt viscosity during capillary extrusion of thermoplastics are reviewed. An initial increase in melt viscosity has been attributed to melt elasticity while three mechanisms are cited to account for a subsequent drop in melt viscosity, which may or may not attain a steady-state value. These are frictional heational heating of the melt, increasing shear stress as the viscometer reservoir empties, and cain orientation. The relative importance of the mechanisms is examined for various melts and the importance of time effects is discussed in terms of their influence on standard flow evaluations, such as the melt index determination.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760060407
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Dependence of mechanical properties in polyolefin blends on shear and thermal history (1981)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 433-438 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Variously dispersed two-component blends of linear polyethylene and a thermoplastic rubber were subjected to different thermal histories after compression molding and their properties were evaluated. It has been shown that ultimate properties of the blends are not defined by the composition, but vary greatly with degree of dispersion and thermal history. Stronger materials failing in a ductile manner were produced under shock cool conditions and in, finely-dispersed blends. Brittle failures and weaker materials were favored by annealing procedures and in blends subjected to brief and/or lowshear dispersion procedures. Time and temperature dependent changes in properties of blends prepared under standard conditions have been observed and activation energies for the aging process calculated. Data interpretation was based on a hypothesis of domain morphology in the blends, and on the existence of “tie molecules” which help to determine the cohesive strength of domain boundaries.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760210710
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Aspects of dispersion and flow in thermoplastic-elastomer blends (1983)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 129-134 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polypropylene, polystyrene, EP (ethylene/propylene) rubber, and bromobutyl rubber were blended under standardized conditions and the sizes of minor phase domains determined by Quantimet analysis. Dispersion effectiveness was found to depend on the melt viscosities of components under mixing conditions and on their “compatibilty” as inferred here from surface-tension data. Dispersion was optimized when components wet readily at contact surfaces and when melt viscosities were similar. Shear heating during dispersion appeared to offer an empirical index of component compatibilty. Apparent melt viscosities of the blends further reflected the component compatibility factor.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760230305
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Flow properties of plasticized PVC: Reduction to composition and interaction variablesPresented at PAG Technical Conference “Design of Experiments and Data Analysis in Plastics Engineering” Chicago September 19, 20, 1968. (1969)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 9 (1969), S. 311-318 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Existing theory of polymer flow has been applied to a definition of shift factors which reduce the widely different melt viscosity/shear rate diagrams of plasticized PVC compounds to well-defined master curves. The master curves are temperature dependent and also define the flow properties of the unplasticized polymer on which a group of plasticized compounds is based. For given plasticizers, the value of the shift factor was found to depend on melt temperature and plasticizer volume fraction. Explicit relationships have been generated for three plasticizer systems; for these, melt viscosity/shear rate data can be precalculated over several decades of shear, and in the temperature range of 150-200°C. Absolute values of the shift factors depend on the type of plasticizer, and a correlation with polymer/diluent interaction parameters has been attempted. Initial results, valid only at high plasticizer volumes and near the reduced melt temperature of a polymer/plasticizer mixture, support the existence of such a correlation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760090411
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Separation of elastic and viscous effects in polymer melt extrusion (1965)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 887-892 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Viscosity and elasticity of polymer melts respond differently to changes in extrusion conditions and to thermal and shear history of the polymer sample. Some reasons for this difference in behavior are summarized in this communication, which also presents new data on the topic. The results are rationalized on the basis of chain flexibility and interaction concepts, permitting the prediction of certain experimentally verifiable aspects of polymer melt rheology.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1965.070090306
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Surface interactions and some properties of filled polymers (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 2269-2280 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Inverse chromatography was applied to evaluate interaction parameters for polyethylene (PE), polyvinyl chloride (PVC), and CaCO3, these parameters being based on retention volumes of proton-donor, -acceptor, and neutral vapors. The acid/base characteristics of CaCO3 were controllably altered by exposing the particulate to microwave plasmas sustained by acidic and basic vapors. It was shown that the ease-of-dispersion of fillers in the polymer matrixes related with the acid-base interaction balance in the polymer-filler pair, and varied widely with the surface treatment given to the filler. Mechanical properties at large deformation of the filled polymers and their durability also were shown to depend on surface interactions. Optimization of properties in PVC compounds was favored when strong acid-base interactions could take place with the plasma-modified filler. In the case of PE, properties were superior when unmodified filler was used; imparting strongly acidic or basic surface properties to the filler diminished its “compatibility” and usefulness with this nonpolar matrix.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070270635
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...