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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 88 (1984), S. 4908-4908 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Fluid inclusion studies of rocks from the late Archaean amphibolite-facies to granulite-facies transition zone of southern India provide support for the hypothesis that CO2,-rich H2O-poor fluids were a major factor in the origin of the high-grade terrain. Charnockites, closely associated leucogranites and quartzo-feldspathic veins contain vast numbers of large CO2-rich inclusions in planar arrays in quartz and feldspar, whereas amphibole-bearing gray gneisses of essentially the same compositions as adjacent charnockites in mixed-facies quarries contain no large fluid inclusions. Inclusions in the northernmost incipient charnockites, as at Kabbal, Karnataka, occasionally contain about 25 mol. % of immiscible H2O lining cavity walls, whereas inclusions from the charnockite massif terrane farther south do not have visibile H2OMicrothermometry of CO2 inclusions shows that miscible CH4 and N2 must be small, probably less than 10mol.%combined. Densities of CO2 increase steadily from north to south across the transitional terrane. Entrapment pressures calculated from the CO2 equation of state range from 5 kbar in the north to 7.5 kbar in the south at the mineralogically inferred average metamorphic temperature of 750°C, in quantitative agreement with mineralogic geobarometry. This agreement leads to the inference that the fluid inclusions were trapped at or near peak metamorphic conditions.Calculations on the stability of the charnockite assemblage biotite-orthopyroxene-K-feldspar-quartz show that an associated fluid phase must have less than 0.35 H2O activity at the inferred P and T conditions, which agrees with the petrographic observations. High TiO2 content of biotite stabilizes it to lower H2O activities, and the steady increase of biotite TiO2 southward in the area suggests progressive decrease of aH2O with increasing grade. Oxygen fugacities calculated from orthopyroxene-magnetite-quartz are considerably higher than the graphite CO2-O2 buffer, which explains the absence of graphite in the charnockites.The present study quantifies the nature of the vapours in the southern India granulite metamorphism. It remains to be determined whether CO2-flushing of the crust can, by itself, create large terranes of largeion lithophile-depleted granulites, or whether removal of H2O-bearing anatectic melts is essential.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 27 (1971), S. 859-860 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Zusammenfassung Insektenjuvenilhormone und -analoge wurden an verschiedenen freilebenden und parasitischen Nematoden getestet. BeiNeoaplectana carpocapsae wurden toxische Effekte und beiCaenorhabditis briggsiae Reifungshemmung festgestellt.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 33 (1984), S. 184-192 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 79 (1982), S. 130-149 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Amphibolite facies metamorphic grade gives way southward to the granulite grade in southern Karnataka, as acid gneisses develop charnockite patches and streaks and basic enclaves develop pyroxenes. Petrologic investigations in the transitional zone south of Mysore have established the following points: 1) The transition is prograde. Amphibole-bearing gneisses intimately associated with charnockite at Kabbal and several similar localities are not retrogressive after charnockite, as proved by patchy obliteration of their foliation by transgressive, very coarse-grained charnockite, high fluorine content of biotite and amphibole in gneisses, and high large-ion lithophile element contents in gneisses and charnockites. These features are in contrast to very low fluorine in retrogressive amphiboles and biotites, very low large-ion lithophile element contents, and zonal bleaching of charnockite, in clearly retrogressive areas, as at Bhavani Sagar, Tamil Nadu. 2) Metamorphic temperatures in the transitional areas were 700°–800° C, pressures were 5–7 kbar, and H2O pressures were 0.1–0.3 times total pressures, based on thermodynamic calculations using mineral analyses. Dense CO2-rich fluid inclusions in the Kabbal rocks confirm the low H2O pressures at the first appearance of orthopyroxene. Farther to the south, in the Nilgiri Hills and adjacent granulite massif areas, peak metamorphic temperatures were 800°–900° C, pressures were 7–9 kbar, and water pressures were very low, so that primary biotites and amphiboles (those with high F contents) are rare. 3) The incipient granulite-grade metamorphism of the transitional areas was introduced by a wave of anatexis and K-metasomatism. This process was arrested by drying out under heavy CO2 influx. Charnockites so formed are hybrids of anatectic granite and metabasite, of metabasite and immediately adjacent gneiss, or are virtually isochemical with pre-existing gneiss despite gross recrystallization to granulite mineralogy. These features show that partial melting and metasomatism are attendant, rather than causative, in charnockite development. Copious CO2 from a deep-crustal or mantle source pushed ahead of it a wave of more aqueous solutions which promoted anatexis. Granulite metamorphism of both neosome and paleosome followed. The process is very similar to that deduced for the Madras granulites by Weaver (1980). The massif charnockites, for the most part extremely depleted in lithophile minor elements, show many evidences of having gone through the same process. A major problem remaining to be solved is the origin of the large amount of CO2 needed to charnockitize significant portions of the crust. The most important possibilities include CO2 from carbonate minerals in a mantle “hot spot” or diapir, from emanations from a crystallizing basaltic underplate, or from shelf sediments trapped at the continent-continent interface in continental overthrusting. Ancient granulite massifs may be such suture zones of continental convergence.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 4 (1971), S. 349-389 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract One of the most promising implications of the phenomenological Ginzburg—Landau (GL) theory of superconductivity is the possible existence of current-carrying metastable states with a negative effective self-inductance. Microscopically this phenomenon can be explained as a result of the depairing mechanism which, when the center-of-mass velocityv s of the Cooper pairs is sufficiently large, can be so strong that a further increase ofv s will lead to a decrease of the total current. Using a one-dimensional formulation of the GL theory we investigate the thermodynamic stability of these states for different external constraints and obtain the result that a negative self-inductance can only be stable if the length of the system in the direction of the current is smaller than a critical value comparable to the GL coherence length λ/κ. It is an experimental fact that states of negative self-inductance are realized in Josephson junctions and other types of superconducting weak links because the dc supercurrent can be a decreasing function of the phase variable φ. The thermodynamic stability theory can therefore explain why weak links have to be short, and it also provides us with a unifying point of view by treating the phase φ and the current as a pair of thermodynamically conjugate variables for arbitrary one-dimensional systems. An important point is the operational phase definition as a thermodynamic parameter that can be controlled by the experimentalist. This requirement is essential for the general validity of the ac Josephson equation and it implies that φ must depend on the magnetic self-inductance of the system. By applying the GL theory to weak links we can delimit the validity of the usual dc Josephson equationI ∝ sin φ and see that deviations from this functional form are most likely to be found in thin-film bridges of the Anderson-Dayem (AD) type. When the currentI is the controlled variable the conjugate phase variable φ will fluctuate and the magnitude of these fluctuations depends strongly on the functional formI(φ). The phase fluctuations for constantI lead to a reduction of the critical current which will be absent when φ is the controlled variable. The observed microwave enhancement of the critical current in AD bridges, the so-called Dayem effect, can be explained as a result of a switch from current control to phase control, and the fluctuation formulae explain why the effect is negligible in structures exhibiting the classical Josephson sine law for the current-phase relation.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 37 (1972), S. 589-607 
    ISSN: 1573-5036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effects were studied of varying amounts and forms of N fertilizers on the chemical composition of soil solution and on the uptake of N, K, Na, Ca and Mg by barley. In isolated soil solution the concentrations as well as the ratios of individual cations depended on form and amount of added nitrogen. The concentration of Σcations increased proportionally with applications of nitrate+sulphate. Cation-activity ratios in isolated soil solution were governed by the ratios of corresponding exchangeable cations. During the entire growth period the absorption by the plants of individual as well as of Σcations was independent of their concentrations in soil solution. So long as NH4 ions were present in the soil solution, plants with NH4 addition contained less Σcations than those with NO3 addition. Thereafter the amounts of Σcations in the plant were closely correlated with N absorption, but not affected by form of applied N. The ratios K/(Ca+Mg) and Ca/Mg in the plant were closely correlated with corresponding activity ratios but independent of concentration ratios of these ions in isolated soil solution. It is postulated that uptake of Σcations is governed by N-metabolic processes in the plant, whereas ratios of absorbed cations are influenced by cation-activity ratios in the soil solution.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 77 (1984), S. 347-365 
    ISSN: 1573-5036
    Keywords: Barley ; Ca ; Cation activity ; Cation activity ratio ; Cation concentration ; Ion uptake ; Mg ; Mustard ; K ; Leek ; Lettuce ; Soil solution ; Spinach ; Uptake capacity ; Uptake ratio ; Net inflow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary In pot experiments with barley, mustard, leek, lettuce and spinach, and in a field experiment with 30 cultivars of barley uptakes of K, Mg, Ca, Na and N were studied at varying concentrations and activities of these cations in the soil solution. The sum of macro cations (K, Mg, Ca, Na) in meq per 100 g aerial plant parts were independent of the chemical composition of the soil solution, but dependent on plant species and on the N concentration in the plant. The ratios $$(\bar I_{Mg} /\bar I_{Ca} and \bar In_K /2(\bar In_{Ca} + \bar In_{Mg} ))$$ of mean net inflows of Mg, Ca and K into plants and corresponding cation activity ratios (aMg/aCa and $$a_K /\sqrt {a_{Ca} + a_{Mg} } $$ ) in the soil solution were linearly related and highly correlated under conditions in which growth rate and/or rate of incorporation into new tissues constituted the rate determining step of cation uptake. Consequently, mean net inflows of K, Mg and Ca were independent of ion concentration and ion activity of K, Mg or Ca in the soil solution under the conditions of constant activity ratio. The results agree with the concept that plants have a finite cation uptake capacity, and that plants are in a equilibrium-like state with the activities of K, Mg, and Ca ions in the soil solution. The results indicate that both ratios and content of exchangeable cations should be considered in our evaluation of soil test data.
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  • 9
    Publication Date: 1984-10-01
    Print ISSN: 0022-3654
    Electronic ISSN: 1541-5740
    Topics: Chemistry and Pharmacology , Physics
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  • 10
    Publication Date: 1971-07-01
    Print ISSN: 0014-4754
    Topics: Biology , Medicine
    Published by Springer
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