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  • Chemistry  (15)
  • Engineering  (2)
  • Wiley-Blackwell  (17)
  • Hindawi
  • 1980-1984  (9)
  • 1970-1974  (8)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 63 (1980), S. 395-401 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Pathway of the Catalytic Reduction of 7-MethylpterinThe catalytic hydrogenation of 7-methylpterin (VII) in a neutral solution occurs first by the reduction of the 7,8-double bond (thermodynamically-controlled reaction) followed by the reduction of the 5,6-double bond. On the contrary, in an acidic medium like CF3COOH, the 5,6-double bond is reduced first (kinetically-controlled reaction). The dihydro-intermediate then undergoes a [1,2]-H-rearrangement leading to the formation of the thermodynamically more stable 7-methyl-7,8-dihydropterin (XV) which on further reduction gives 7-methyl-5,6,7,8-tetrahydropterin (VIII). The catalytic reduction of 7-methyl-7,8-dihydropterin (XV) with deuterium gives stereoselectively a sole product with D at C(6) in the equatorial position.
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 63 (1980), S. 1754-1758 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Pathway of the Catalytic Reduction of 6-MethylpterinThe catalytic hydrogenation of 6-methylpterin (I) in neutral or weekly acidic solution begins, as for the 7-methylpterin, by the thermodynamically controlled reduction of the 7,8-double bond. It is not possible to say, according to our experiments, which double bound, either the 5,6 or the 7,8, is first reduced in strongly acidic solution. However, a 5,8-reduction can be excluded.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 183 (1982), S. 1093-1099 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: N-Vinylcarbazole (NVC) is polymerised in the presence of pyridine at 60°C by using azodiisobutyronitrile (AIBN) and benzoyl peroxide (Bz2O2) as initiators and the results are compared with those obtained when benzene is used as the solvent. In the AIBN-initiated system using pyridine as the solvent the rates of polymerisation follow an usual linear relationship with respect to monomer concentration and a square root dependence with respect to the initiator concentration. In the Bz2O2-initiated system, however, deviations from these ideal behaviours are observed when benzene and pyridine, respectively, are used as the solvent. Initiation occurs through the complexation of the monomer with Bz2O2 and degradative transfer is thought to be mainly responsible for this unusual kinetic behaviour.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 19 (1983), S. 1183-1192 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The results of the finite element analysis of 3-ply laminated conical shells with light core for linear panel flutter are presented and certain advantages of such shells discussed.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 26 (1984), S. 188-190 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 1565-1594 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The observed Raman and ir spectra of Ca-poly(L-glutamate) in the β conformation have been analyzed by means of a normal mode calculation. The force field for the main chain was transferred without refinement from β-poly(L-alanine), yet it provides a good prediction of the observed bands and, in particular, explains subtle differences in the spectra of these two β-sheet structures. Main- and side-chain modes are well characterized, and the dependence of the amide III frequency on side-chain composition is again demonstrated.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 15 (1971), S. 1599-1605 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In the present paper we have analytically derived a single-point equation for determining the intrinsic viscosity of a polymer. It is observed that the proposed equation gives a much better agreement with the extrapolated value of [η] over a wide range of concentration for good as well as poor polymer-solvent systems.
    Additional Material: 2 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 379 (1970), S. 106-111 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wird die Darstellung von Hydroxotrifluoroboraten von Rb, Cs, (CH3)4N+, Nitron, Ni2+, Ni(py)42+ und Co(NH3)63+ beschrieben. Darüber hinaus wurden neuartige 1 : 1-Doppelsalze aus Tetrafluoro- und Hydroxotrifluoroborat erhalten. Von einigen dieser Salze werden Röntgenpulver- und IR-Daten mitgeteilt.
    Notes: The preparation of monohydroxotrifluoroborates of rubidium, cesium, tetramethylammonium, nitron, nickel, tetrapyridine nickel and hexammine cobalt(III) is described. Besides, a new series of double salts, comprising one mole tetrafluoroborate and one mole of monohydroxotrifluoroborate of the same cation, are described. The X-ray and IR-spectra of some of these salts are reported.
    Additional Material: 3 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 390 (1972), S. 61-63 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Darstellung der Dioxitrifluorovanadate, MI2 (VO2F3)(M = Na+, NH+4, 1/2Ni2+) und MII(HVO2F3)2· xH2O (M = Cu2+, Ni2+, Co2+) wird beschrieben. Leitfähigkeitsmessungen von K2VO2F3 in verschiedener Konzentration deuten auf eine Dissoziation 2K+-und VO2F2-3-Ionen.
    Notes: Preparation of the salts of the series dioxotrifluorovanadates, M2I (VO2F3), where M = Na+, NH+4, 1/2Ni2+ and MII(HVO2F3)2· xH2O where M = Cu2+, Ni2+ and Co2+ are described. Molecular conductivity measurement of potassium dioxotrifluorovanadate(V), K2VO2F3, at different dilutions indicates that it dissociates primarily into 2K+ and VO2F2-3 ions.
    Additional Material: 1 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 384 (1971), S. 255-259 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Ammonium-, Natrium-, Hexamminkobalt (III) und Åthylendiaminium-dioxofluorovanadat(V), MIVO2F2. wurden dargestellt und durch Röntgenpulveraufnahmen, IR-Spektrum und im Falle des NH4-Salzes-Thermogravimetrie charakterisiert.
    Notes: The syntheses of ammonium, sodium, hexamminecobalt(III) and ethylene-diamine dioxodifluorovanadate(V), MIVO2F2, are reported. Their x-ray powder diffraction data are different from those of the corresponding tetrafluoroborates and perchlorates. Their infrared spectra have been recorded (700-4000 cm-1), and probable band assignments made. The ammonium dioxodifluorovanadate has been studied through thermogravimetry, and the composition of an intermediate product is discussed from its chemical analysis and infrared spectrum.
    Additional Material: 1 Ill.
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