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  • Polymer and Materials Science  (8)
  • Superfluidity and superconductivity
  • Temperature of maximum density of water
  • 1980-1984  (3)
  • 1975-1979  (6)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 10 (1981), S. 351-356 
    ISSN: 1572-8927
    Keywords: Temperature of maximum density of water ; conductance ; potassium halides ; mobilities ; Walden product ; structural effects ; activation energy ; temperature dependence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The conductances of dilute aqueous solutions of KCl, KBr, and KI have been measured over the temperature range 2 to 8°C and have been analyzed by the Fuoss-Hsia equation. The ionic Walden products at infinite dilution have been discussed in terms of local viscosity. The temperature dependence of these products suggest that near the temperature of maximum density of water, the structure-breaking ability of these ions changes in a regular way.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 176 (1975), S. 1121-1128 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Äthylen-Propylen Copolymere, die mit spezifisch syndiotaktischen Katalysatoren dargestellt werden, enthalten sowohl Kopf-Schwanz als auch Schwanz-Kopf orientierte Propyleneinheiten. Daher ist diese Copolymerisation eigentlich eine Terpolymerisation und die einfache Propylenpolymerisation eine binäre Copolymerisation.Die sich daraus für die Kinetik der Polymerisation und Copolymerisation ergebenden Konsequenzen werden untersucht.
    Notes: Ethylene-propylene copolymers prepared with syndiotactic specific catalysts contain both head-to-tail and tail-to-head oriented propylene units. Consequently, this copolymerization is, actually, a terpolymerization, and the propylene polymerization is a binary copolymerization.The consequences of this fact on the kinetics of polymerization and copolymerization are considered.
    Additional Material: 1 Ill.
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  • 3
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In order to elucidate the relations between morphological habits, thermal behaviour and chemical structure of polymers, aliphatic polyesters with variable amount of trans-double bonds along the backbone chain were crystallized from dilute solutions in 1-propanol and 1-butanol. The crystals were studied with electron microscopy, differential scanning calorimetry, and wide angle X-ray diffraction. The morphology of solution grown single crystals and some thermodynamic quantities such as the equilibrium dissolution and melting temperature and the enthalpy and entropy of fusion are influenced by the percentage of unsaturated comonomer. The thermal behaviour and the X-ray diffraction of these crystals suggest that saturated and unsaturated repeating units are able to cocrystallize.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 180 (1979), S. 1037-1040 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the present paper we have investigated the role that the presence of trans double bonds plays on the glass transition temperature of linear polyesters. Experimental data indicate that the glass transition temperature is increased by an increase of the unsaturation concentration. The effect is not drastic but it is well detectable. This result is discussed taking into account the chain microstructure and the bulk structure effects.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 181 (1980), S. 1339-1348 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Copolyesters derived from adipic acid, trans-3-hexenedioic acid and 1,16-hexadecanediol were prepared and investigated by means of X-ray diffraction and DSC techniques. From the X-ray results an isomorphous replacement of the saturated and unsaturated diacid units has been suggested. The equilibrium melting temperature Tm0 and the heat of fusion ΔHf were slightly dependent on the copolyester composition. The crystallization process was analyzed by means of Hoffman's kinetic crystallization theory for a lamellar type crystal growth. The values of the free energy of formation of a nucleus of critical dimensions φ* and the free energy of folding σe were found to decrease regularly with increasing amount of double bonds, varying from 110 to 83 kJ/mol for Δφ* and from 171 to 127 erg/cm2 for σe. This effect has been interpreted on the basis of an increase of chain flexibility owing to the presence of the trans double bonds.
    Additional Material: 7 Ill.
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  • 6
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic mechanical behaviour of polyamide systems containing different degrees of unsaturation was analyzed. The results do not show any simple relation between unsaturation and mechanical response. Particular attention was given to the α-transition, that is a glass transition, and experimental data suggest that the generally accepted mechanism for this transition requires a more extensive study.
    Additional Material: 3 Ill.
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  • 7
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic mechanical properties of ethylene/propylene copolymers prepared by soluble catalysts based on vanadium salts and alkylaluminium compounds were investigated. The properties of the copolymers were found to depend not only on the chemical composition, but also on the polymerization temperature and on the stereoregulating character of the catalyst. The mechanistic implications of these findings are discussed.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 62 (1977), S. 85-90 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Reaktivität verschiedener monomerer Vinylketone bei der radikalischen Copolymerisation mit Methylmethacrylat und Vinylacetat wurden auf der Basis der Taft-Gleichung untersucht. Es ergab sich, daß die relative Reaktivität der Vinylketonmonomeren mit zunehmender Elektronegativität der Substituenten der verschiedenen Vinylketone steigt. Polare und sterische Effekte beeinflussen die Reaktivität nicht.
    Notes: The reactivity of some monomer vinyl ketones in the radical copolymerization with methyl methacrylate and vinyl acetate was studied on the basis of the Taft equation. It was concluded that the relative reactivities of the vinyl ketones in radical reactions increase with increasing electron-withdrawing nature of the vinyl ketone substituent. Polar and steric effects do not affect the reactivity.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1809-1822 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Random polyesteramides with different chemical compositions and block polyesteramides have been prepared by a two-step polycondensation method from adipolyl dichloride, 1,10-decandiol, and 1,6-diaminohexane. A sample of alternating microstructure has been synthesized by melt polycondensation of 1,10-decandiol and preformed bisesteramides. The thermal and viscoelastic behavior has been investigated and related to the chemical composition and chain microstructure. The random copolymers exhibit one transition in the crystalline phase, whereas two transitions are shown by the block copolymers. The viscoelastic behavior suggests that in the amorphous component a partial microsegregation of phase occurs, generating an intermediate structure between a monophasic and a biphasic amorphous system.
    Additional Material: 9 Ill.
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