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  • Articles  (212)
  • Chemical Engineering  (161)
  • Cells, Cultured  (51)
  • Physical Chemistry
  • 1980-1984  (138)
  • 1975-1979  (74)
  • Physics  (212)
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  • Articles  (212)
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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 660-667 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The operation of a twin screw extruder processing a powder or granular solid is reviewed. The operating variables of screw speed and barrel temperature profile interact with a number of design parameters -  screw design, die geometry, feed zone geometry and with the material properties, in determining machine performance. The factors that determine output and pressure development are specified in a sequence of block diagrams. The dynamic response of an operating machine to disturbances in the steady state conditions is explained in the light of the established relationships and interpreted in conventional control theory terms. Attention is drawn to the importance of mixing in the chambers formed by the screw channels and of the residence time distribution in determining the quality of the final product.
    Additional Material: 14 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 280-286 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of two characterized linear polyethylenes with a branched polyethylene have been prepared by melt extrusion. It has been found that the linear polyethylenes can be shear modified in a reversible manner similar to branched polymers and that this shear modification and its reversal by re-heating does not change the molecular weight distribution, thereby indicating that the shear modification is a physical rather than chemical change in structure. Because both the high- and low-density polyethylene components of the blends are capable of undergoing reversible shear modification, it is possible to produce blends with either greater or less melt elasticity than the individual components by adjusting the conditions of blending. This demonstrates that the correlation of the properties of blends with the properties of their components should not be attempted without consideration of the effect of the blending process on the properties of the individual components.
    Additional Material: 14 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 229-233 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this work, the exchange reaction taking place in molten blends of bisphenol-A polycarbonate and polybutylene terephthalate was studied. A direct transesterification mechanism catalyzed by titanium residues, present in commercial PBTP, was deduced. The transesterification reaction can be -stopped at various levels by additives capable of complexing the titanium catalyst.This work enhances the possibility of a new approach in macromolecular engineering by directly combining polycondensates in a processing machine such as an extruder.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 537-542 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hydrolytic stability of glass fiber reinforced poly(butylene terephthalate) (PBT), poly(ethylene terephthalate) (PET) and polycarbonate (PC) was studied. The activation energies in kcal/mole for hydrolysis are 26 for PBT and 23 for PET. Both PBT and PET contain 30 percent glass fiber reinforcement. The hydrolysis rates for a series of experimental PC's containing 10, 30 and 40 percent glass were obtained from GPC data. These increase with glass concentration but are lower than that of the unreinforced PC. Melt flow rate changes are a good measure of the hydrolytic degradation of PET. However, in the time scale of these experiments, the tensile properties of glass reinforced PBT and PC do not correlate well with M̄w changes, unlike unreinforced PBT and PC polymers. Consequently, to compare these three glass fiber reinforced polymers, estimates of failure time must be based on changes in tensile strength rather than melt flow rate.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 299-305 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: One of the problems to be considered in the application of the Halpin-Kardos theory to crystalline polymers is the relation of the crystal length to the only related and measurable parameter, spherulite size. The number average crystal length has been computed for various two and three dimensional models for the crystallization process assuming heterogeneous nucleation. It was found that high values of crystallinity are consistent only with lamellae that are stacked in a parallel fashion. For these systems the number average lamellar length is 0.55 of the spherulite radius. Lower crystallinity polymers have an average lamellar length 0.3 to 0.5 of the spherulite radius, the actual value being determined by the radius. For spherulites of radius 1μm or greater, the size of the primary nucleus has no noticeable influence on the average lamellar length.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 869-874 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of time of indentation and time of recovery on the Rockwell hardness, of a series of glassy and crystalline polymers has been determined. An analytical technique, based on conventional viscoelastic approaches, has been developed. This technique permits the resolution of the hardness number into its components of permanent deformation, retarded elastic compression, and retarded elastic recovery. Subtraction of components due to retarded elastic response results in hardness numbers dependent only the time-dependent permanent deformation. Extrapolation of this data to zero time results in an absolute or time-independent value of Rockwell hardness, designated Ro.
    Additional Material: 14 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 260-264 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hydrolytic stability of poly(butylene terephthalate) (PBT) resins and compounds was studied. Rates of reaction were determined by measuring changes in melt flow rate. Hydrolysis was slightly accelerated by contact of PBT with glass containers and reduced by incorporation of some flame retardant additives. Melt flow rates were related to tensile elongation ofunfilled PBT and tensile strength ofthe glass fiber reinforced polymer and used as failure criteria. Reaction rates were used to predict failure times at various conditions.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 86-92 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental investigation into the performance in general and the melting behavior in particular of a single screw extruder running with a low density polyethylene power has been carried out and the results compared with those for a granular feedstock of low density polyethylene having similar melt properties. It was found that the tendency was for the output rate, pressure generated and specific power consumption to be lower for the powders, and that the removal of barrel heating near the feed hopper increased these parameters. Two melting mechanisms were observed in powder extrusion; one being the classic “Maddock” type, and the other such that the solid bed and melt pool were in reversed positions relative to the Maddock case. There was a trend for this latter mechanism to operate with low screw speeds, shallow channels and full heating. Melt initiation occurred nearer the feed end and melting was completed much more quickly with powders. An explanation of the mechanisms is proposed which is based on the observation of early melt initiation, and the industrial practices of feed zone cooling and increasing feed pressure generation to improve the performance of extruders running with powders are seen to be consistent with this proposition.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 185-188 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(vinyl chloride) and chlorinated poly(vinyl chloride) films were saturated at 100°C with fluorotrichloromethane (Genetron-11, a foaming agent) and then allowed to desorb at RT and 65°C. The desorption data for a three month period was fitted into a mathematical relationship which could be used for long term predictions of the G-11 retention in the films. Using thermoanalytical techniques, plots of glass transition temperature vs G-11 concentration were made for the polymers under study. These plots were used to demonstrate the effect of stabilizer, polymer type and temperature on the desorption of the G-11.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 370-375 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A number of commercially available polycarbonates, including formulations made flame retardant by two different modifications, have been exposed to conditions producing moderately rapid hydrolysis. Hydrolysis rates were calculated from molecular weight data determined by gel permeation chromatography and, in some cases, from melt flow rate data. The rates calculated by the two methods are in good agreement. In general, the standard formulations containing minimal additive packages are the most hydrolytically stable. Although one relatively new flame retardant polycarbonate demonstrates generally good resistance to hydrolysis, most of the flame retardant formulations appear to be quite susceptible to hydrolytic degradation. For these materials, hydrolysis under conditions encountered in use could cause significant decreases in impact strength within a few years.
    Additional Material: 3 Ill.
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