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  • Polymer and Materials Science  (42)
  • Anisotropy  (1)
  • 1980-1984  (32)
  • 1975-1979  (11)
  • 11
    Electronic Resource
    Electronic Resource
    Studies on carbazole based polyarylates (1981)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 97 (1981), S. 79-90 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde ein neues Polyarylat aus Carbazol und Resorcinol nach der Methode der Lösungskondensation bei niedriger Temperatur unter Verwendung von Pyridin als Katalysator hergestellt. Das Polymere wurde im Hinblick auf seine Struktur, thermische Stabilität und sein dielektrisches Verhalten charakterisiert. Der Einfluß des Diphenolenteils auf die thermischen und dielektrischen Eigenschaften dieses Polyarylats und anderer auf Carbazolbasis wurde untersucht.
    Notes: A novel polyarylate has been synthesized from carbazole and resorcinol by low temperature solution condensation method using as an acceptor-catalytic reagent pyridine. It has been characterized in respect of its structure, thermal stability and dielectric behaviour. The influence of the diphenol moiety on the thermal and the dielectric properties of this polyarylate and the others based on carbazole has been studied.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1981.050970107
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  • 12
    Electronic Resource
    Electronic Resource
    Chemical modification of polystyrene, III. Electrophilic substitution of polystyrene with aromatic anhydrides (1983)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 113 (1983), S. 11-19 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Polystyrol wurde durch Friedel-Crafts-Acylierung mit Trimellithsäureanhydrid in Gegenwart von wasserfreiem Aluminiumchlorid als Katalysator chemisch modifiziert. Das Produkt wurde hinsichtlich seiner Struktur und physikalisch-chemischen Eigenschaften durch Messung der Gesamtkapazität, der thermischen Stabilität und des Titrationsverhaltens charakterisiert. Die thermischen Kenngrößen des mit Trimellithsäureanhydrid modifizierten Polystyrols wurden im Hinblick auf ihre strukturellen Eigenheiten mit denen des mit Phthalsäureanhydrid und mit Pyromellithsäuredianhydrid modifizierten Polystyrols verglichen.
    Notes: Polystyrene has been chemically modified by Friedel-Crafts acylation reaction with trimellitic anhydride in the presence of anhydrous aluminium chloride as catalyst. The product has been characterized in respect of its structure and physicochemical properties by measuring its total capacity, thermal stability and the behaviour to pH metric titration. The thermal characteristics of the trimellitic anhydride modified polystyrene have been compared with the same for phthalic anhydride and pyromellitic dianhydride modified polystyrene in the light of their structural characteristics.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1983.051130102
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  • 13
    Electronic Resource
    Electronic Resource
    Furfural-based phosphonic acid cation exchange resins from N-vinylcarbazole and its polymer. II (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 161-169 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal stabilities of the crosslinked N-vinylcarbazole/poly(N-vinylcarbazole)-furfural polymers and of the phosphonic acid resins prepared thereform were studied by thermogravimetric analysis. The overall thermal stability of the crosslinked polymers is greater than the same for poly(N-vinylcarbazole) and is further improved upon phosphorylation. The resins are stable in 5N acids and water at 100°C. Isothermal oxidative degradation studies of the resins indicate significant increase in the capacities. pH metric titration of the resins shows the presence of mono and dibasic phosphonic acid groups. The resins realize about 90% of their capacities within 2 min of equilibration.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070270118
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  • 14
    Electronic Resource
    Electronic Resource
    Chemical modification of polystyrene. II. A cation exchange resin from polystyrene electrophilically substituted with pyromellitic dianhydride (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4645-4653 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crosslinked polystyrene based on condensation of polystyrene and pyromellitic dianhydride has been processed into a sulfonic acid cation exchange resin of improved thermal properties. The resin has been characterized in respect to its structure ion exchange and thermal stability by IR and elemental analysis data, total and salt-splitting capacity measurements, pH-titration characteristics, and TGA and DTA studies.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070271211
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  • 15
    Electronic Resource
    Electronic Resource
    Some observations on the thermal stabilities of modified N-vinylcarbazole polymer systems (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1823-1825 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070270537
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  • 16
    Electronic Resource
    Electronic Resource
    Furfural-based cation-exchange resins from N-vinylcarbazole and its polymer (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2327-2334 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cation-exchange resins have been synthesized through the condensation of N-vinylcarbazole and poly(N-vinylcarbazole) with furfural in presence of anhydrous AlCl3 and subsequent sulfonation of the condensates. The resins have been characterized in respect to their polyfunctionality, exchange capacity, and thermal stability.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230810
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  • 17
    Electronic Resource
    Electronic Resource
    Phthalic anhydride-based cation exchange resin from N-vinylcarbazole (1980)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 511-518 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A condensation product based on phthalic anhydride and N-vinylcarbazole has been prepared and processed into a sulfonic acid cation exchange resin. The resin produced has been characterized by measuring its total and salt splitting capacities and by studying its thermal characteristics, rate of exchange, and behavior to pH metric titration.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1980.070250316
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  • 18
    Electronic Resource
    Electronic Resource
    Cation exchange resin from sulfonated N-vinylcarbazole and divinylbenzene copolymer (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 1719-1725 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A copolymer of N-vinylcarbazole and divinylbenzene has been sulfonated to yield a cation exchange resin of improved thermal properties compared to other vinylcarbazole-based resins. The resin has been characterized by measuring its total and salt-spliting capacities, pH metric titration, and thermal stability characteristics.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260526
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  • 19
    Electronic Resource
    Electronic Resource
    Crosslinked polymer from N-vinylcarbazole and formalin (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1183-1186 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A crosslinked polymer has been synthesized from the reaction of N-vinylcarbazole and formalin in toluene in the presence of dry HCl gas. The copolycondensate is insoluble in all common solvents for poly-N-vinylcarbazole, and exhibits higher thermal stability than the unmodified poly-N-vinylcarbazole. However, this polymer is less thermally stable than the corresponding furfural modified poly-N-vinylcarbazole. A mechanism for the overall reaction has been suggested and the factors affecting the synthesis have been discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290414
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  • 20
    Electronic Resource
    Electronic Resource
    Cation exchange resin from sulfonated poly-N-vinylcarbazole-formaldehyde copolymer (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1999-2005 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A cross-linked copolymer of poly-N-vinylcarbazole and formaldehyde has been sulfonated to yield a cation exchange resin. The resin has been characterized by elemental analysis and by evaluation of total and salt-splitting capacities and pH-metric titration behavior. The resin has improved capacity (ion exchange) relative to other N-vinylcarbazole based resins and behaves as a polymeric dye.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290608
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