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  • METEOROLOGY AND CLIMATOLOGY  (14)
  • Analytical Chemistry and Spectroscopy  (3)
  • Male
  • 1980-1984  (12)
  • 1975-1979  (6)
  • 1
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Using appearance potential measurements it is shown that chain length effects in the formation of the title ions can be assigned to an entropy and energetic factor. In addition it is demonstrated that the genesis of the stable [M-PhO]+ ions proceeds via a transition state resulting in the formation of cyclic structures. Acyclic structures or complex rearrangements of the carbon skeleton can probably be excluded.
    Notes: Mit Hilfe von Auftrittspotentialmessungen wird belegt, daß die bei der Bildung der Titel-Ionen beobachteten Kettenlängen-Effekte sowohl durch entropische als auch energetische Faktoren gesteuert werden. Zusätzlich wird gezeigt, daß die Genese der stabilen [M-PhO]+-Ionen - unabhängig von der Kettenlänge der reaktiven Molekül-Ionen-über einen Übergangszustand erfolgt, der zu cyclischen Produkten fiihrt. Acyclische Spezies oder solche, die durch komplexe Umtagerung des Kohlenstoffgerüstes entstehen könnten, sind wahrscheinlich auszuschließlen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1978), S. 243-249 
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectrometric sensitivity data for the compounds cholesterol, cholestane, DDT, decafluorotriphenyl-phosphine, morphine, LSD and methyl stearate have been developed over a period of time and under a variety of conditions. This information is presented on both a relative and an absolute basis. With the exception of morphine, relative sensitivities were repoducible to within a factor of three over a six month period. This reproducibility facilitates quantitation and a single standard can be used for calibration of organic compounds from various classes. Detection limits of 50 femtograms for LSD are realized for samples introduced via the direct inlet probe.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 11 (1981), S. 493-495 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Low frequency Raman scattering of aqueous solutions of disodium-5′-guanosine monophosphate (GMP), dipotassium-5′-GMP, NaCl and KCl are studied by construction of a quantity R(ν). A band with a maximum at 115 cm-1 is assigned to a mode from mononucleotides, associated in a manner different from normal base stacking.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 1978-10-20
    Description: Five Japanese macaques and five other Old World monkeys were trained to discriminate among field-recorded Japanese macaque vocalizations. One task required discrimination of a communicatively relevant acoustic feature ("peak"), and a second required discrimination of an orthogonal feature of the same vocalizations ("pitch"). The Japanese animals more proficiently discriminated the peak feature when stimuli were presented to the right ear (primarily left cerebral hemisphere), as opposed to the left ear (primarily right hemisphere). In discriminating the pitch feature, the Japanese animals either showed (i) a left-ear processing advantage or (ii) no ear advantage. The comparison animals, with one exception, showed no ear advantage in processing either feature of the vocalizations. The results suggest that Japanese macaques engage left-hemisphere processors for the analysis of communicatively significant sounds that are analogous to the lateralized mechanisms used by humans listening to speech.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Petersen, M R -- Beecher, M D -- Zoloth, S R -- Moody, D B -- Stebbins, W C -- New York, N.Y. -- Science. 1978 Oct 20;202(4365):324-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/99817" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Auditory Perception/*physiology ; Discrimination Learning/physiology ; Female ; *Functional Laterality ; Haplorhini ; Macaca/*physiology ; Male ; Species Specificity ; Vocalization, Animal/*physiology
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Publication Date: 2011-08-19
    Description: Infrared and visible imagery from VAS are used to delineate mid- and lower-tropospheric moisture fields for a variety of severe storm cases in the southern and central United States. The ability of sequences of images to isolate areas of large negative vertical moisture gradients and apparent convective instability prior to the onset of convective storms is assessed. A variety of image combination procedures are used to deduce the stability fields which are then compared with the available radiosonde data. The results for several severe storm cases indicate that VAS can detect mid- and low-level mesoscale water vapor fields as distinct radiometric signals. The VAS imagery shows a strong tendency for thunderstorms to develop along the edges of bands of midlevel dryness as they overtake either preexisting or developing low-level moisture maxima. Image sequences depict the speed with which deep moist and dry layers can develop and move.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Monthly Weather Review (ISSN 0027-0644); 112; 2178-219
    Format: text
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  • 6
    Publication Date: 2011-08-18
    Description: The information content of the VAS radiances can be converted to meteorological parameters useful for analyzing a severe weather environment. The method by which the VAS variances are converted to vertical profiles of temperature, dewpoints, and equivalent potential temperature involves a basic regression technique using the most local radiosonde data available for establishing a correlation matrix. The results indicate that mesoscale features apparent within images of the radiances can be converted to usable temperature and moisture fields using regression when surface temperature and dewpoint observations are included within the total data base. In addition, results indicate that surface data are very important for better defining lower tropospheric structure that the VAS radiances alone cannot properly resolve. Analyses of these retrievals distinctly show mesoscale structure in the temperature and moisture fields derived with VAS radiances collected every 3 hours, and 0000 GMT. The retrievals capture the moisture structure. More important, convective instability is clearly detected immediately before the onset of convection. The results indicate that the VAS is capable of providing valuable mesoscale information suitable for analyzing a preconvective environment that is generally clear.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: VISSR Atmospheric Sounder (VAS) Res. Rev.; p 9
    Format: text
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  • 7
    Publication Date: 2011-08-18
    Description: The utility of combining visible and various infrared images from the VAS to produce a forecasting tool, that can be available on a near real time basis, to predict severe weather development is shown. Areas where dry air in the midtroposphere overlays substantial moisture at low levels are used to diagnose mesoscale regions that have the potential for being convectively unstable before the onset of severe convection. Specifically, 6.7 micron water vapor imagery, used for isolating regions of substantial midlevel dryness, are combined with images of low level clouds or with split-window low level moisture images to delineate regions that have the potential for convective instability. In areas where scattered low level clouds are present, computer generated, color image combinations are used to isolate those warm, low level clouds that are in potential convectively unstable environments from clouds that exist under a deeply moist atmosphere. In clear regions, the split window technique is used for delineating areas of substantial boundary layer moisture. These images are again computer overlayed by the midlevel dryness to produce a color coded image of potential convective instability.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: VISSR Atmospheric Sounder (VAS) Res. Rev.; p 7
    Format: text
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  • 8
    Publication Date: 2011-08-19
    Description: Wind field forecasts, based on data from the Visible Atmospheric Sounder (VAS) instrument on board the most recent GOES satellite, are described. The forecasts were used to generate a series of water vapor images for the Central U.S. according to an isentropic prediction scheme. The ability of VAS imagery to detect regions of mesoscale convective instability was contrasted with data from a 9-12 hr advective forecast and the results are discussed. It is shown that the VAS imagery was free from masking by convective outflows and lends itself to repeated applications for updating throughout the day. The incorporation of surface data into the VAS forecast is recommended in order to identify areas of persistent moisture convergence. Some examples of the VAS imagery are provided.
    Keywords: METEOROLOGY AND CLIMATOLOGY
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  • 9
    Publication Date: 2019-06-28
    Description: Wind data taken from 10 levels between 18 and 305 m were examined to determine the properties of atmospheric turbulence within and above the atmospheric surface layer into the PBL. The samples were averaged over 40 min intervals, with all periods of rain, fog, and other disturbances being eliminated from the 16 days of monitoring. Turbulence spectra were calculated using a fast Fourier transformation. The tower was located in rolling terrain covered with pine forests, waist-high scrub, and cultivated fields. Results are presented for the wavelength and Eulerian length scales, considering the neutral, stable, and unstable PBL. Correlation coefficients were found between velocity fluctuations and wavelengths for the stability classes. Good agreements were found for measured and computed spectra in all but unstable conditions.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Applied Meteorology; 21; Nov. 198
    Format: text
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  • 10
    Publication Date: 2019-06-27
    Description: An explicit technique for calculating atmospheric trajectories is presented as an alternative method to the standard implicit scheme of Danielsen (1961). The technique uses the inviscid equations of motion and the discrete model formulation derived by Greenspan (1972, 1973) to compute trajectories on isentropic surfaces, assuming adiabatic flow. The discrete model formulation is designed specifically for a Lagrangian system and objectively accounts for the geostrophic departures, local psi-tendencies, and the subsequent accelerations along the entire length of the trajectory. Application of the discrete formulation to a diagnostic case study yielded favorable results.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Monthly Weather Review; 107; May 1979
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