ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract An electron impact technique has been used for the direct determination of the ionization potential (IP) of the ClO3 radical and the electron affinity (EA) of the ClO3 and ClO4 radicals. By means of quantum-chemical calculations taking into account configuration interaction within the framework of the third-order perturbation theory of Miller and Plesset, it has been shown that, for this class of compounds, upon ionization, there are no significant excess energies related to processes of isomerization and electronic excitation. The theoretical and experimental values of the IP and EA are in agreement within 0.5 eV.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00962114
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