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  • 1985-1989  (2)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 329 (1987), S. 775-779 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Me⊕ (Me = Na; K) cations in MeClO3 chlorates were complexed by crown ethers (CE): 12C4, 15C5 and 18C6 in solution. In the solid phase we could obtain only Na(15C5)ClO3 and K(18C6)ClO3 complexes significant shift in 35Cl-n.q.r. frequency with respect to the frequency of pure sodium and potassium chlorates was observed. The shifts at 77K were -2.879 MHz for Na(15C5)ClO3 and -1.004 for K (18C6)ClO3.For other reaction mixtures the 35Cl-n.q.r. frequencies observed were the same as for the appropriate pure chlorates which confirmed that the expected complexation in the solid phase had not occurred. The investigation described in this paper proved a rapid increase in selectivity of crown ethers at the transition from the solution to the solid state. Moreover, in the solid phase of Me(CE)ClO3 complexes a significant increase was found in the shielding effect of the Me⊕ cation by the surrounding crown ether.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 1985-04-01
    Description: SummaryTwo experiments were conducted with eight rams in a latin-square design of four treatments with different lucerne hay (LH): maize grain (MG) ratios: 100:0, 80:20, 50:50 and 20:80. In Expt 1 the amount of food offered was restricted to 1 kg/day. In Expt 2 the rams were offered 1·5 kg/day, which was about the maximum amount the animals in the 100% LH treatment were able to consume. Animals were kept on each treatment for 4 weeks; during the final 8 days the faeces were oollected and weighed for each animal and analysed for dry matter, organic matter (OM), crude fibre and δCThe values of δC in LH, MG and different faeces samples were used for direct determination of LH and MG digestibilities of mixed diets in the different treatments.The increase of MG in the ration and the decrease of LH improved the digestibility of total OM. The effect of MG was more pronounced at the low than at the high level of consumption. At the low level of intake, an increase in the amount of MG in the ration did not affect the digestibility of LH, and MG digestibility was close to the extrapolated value. At a food intake level 1·5 times that of Expt 1, the addition of grain to more than 50 % of the ration caused a marked depression in digestibility of LH.Results of the δC method were discussed in comparison with calculated values of LH and MG digestibilities and with whole ration crude-fibre digestibility.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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