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  • Articles  (22)
  • 1985-1989  (22)
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  • Articles  (22)
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  • 1
    Publication Date: 1988-03-01
    Print ISSN: 0025-326X
    Electronic ISSN: 1879-3363
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Elsevier
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 92 (1988), S. 2362-2366 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 7492-7501 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have applied the polarizable electropole model of water and of water–ion interaction to molecular dynamics simulations of aqueous microclusters of alkali metal cations and halogen anions in the temperature range 150–400 K. This model effectively correlates observed enthalpies of formation; it is especially reliable for the larger alkali metal cations. Our simulations show unambiguous evidence of hydrogen atom inequivalency in the anion mono- and dihydrates over the temperature range studied. For the analogous cation hydrates, the structures are symmetric. We find two solvation shells in the larger microclusters; the largest ions have the fewest water molecules in their first solvation shells. The iodine and cesium inner solvation shells appear to contain only three and four water molecules, respectively. The structure of the anion hydrates strongly suggests that their stability arises in part from water–water binding.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 27 (1988), S. 9020-9030 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 91 (1987), S. 6582-6591 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 4045-4051 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have applied the polarizable water model to molecular dynamics simulations of water microclusters of alkali metal cations and halogen anions. We find that this model, with two adjustable parameters, yields stabilization energies in good agreement with Hartree–Fock calculations and with experimental data. Several new, low energy, less symmetric configurations of the ion–water microclusters are obtained. These are particularly favored by the larger, more polarizable ions.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 77 (1988), S. 285-294 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract Deduced from empirical and theoretical work, a model is proposed for the rheology of bi- and polyphase rocks based on the rheology of the components, their volume fractions, and their geometrical distribution. The model is formulated for the common case where some minerals deform by crystall plasticity at steady state and others, stronger ones, deform in the vincinity of the brittle-ductile transition. The model results from a combination of a load-carrying framework model and a two-block model. The first model is valid for the field, where stress is mainly accommodated by interconnecting stronger phases. The second model describes the case where strain is concentrated mainly within the weaker phase. The transition-point from one partial-model to the other depends on the material properties of the minerals involved. With increasing strain, it shifts first to higher then to lower contents of weaker materials, due to an increase of contrast in competence and to the development of a mechanically induced compositional foliation. Finally, the rheology of the resulting well foliated rock is dominated by the rheology of the weakest component.
    Abstract: Résumé L'auteur, à partir de données empiriques et de travaux théoriques, présente un modèle de la rhéologie des roches biet poly-phasées, dans lequel cette propriété apparaît comme une fonction de la rhéologie de chacune des phases, des proportions en volume de celles-ci et de leurs relations géométriques. Ce modèle s'applique au cas le plus répandu dans lequel certains minéraux ont un comportement proche de la transition cassant-ductile, tandis que les autres fluent plastiquement à contrainte constante à l'intervention de processus intra-cristallins. Le modèle est la synthèse de deux modèles partiels. Le premier correspond au cas où la phase compétente forme un squelette absorbant la plus grande part de la contrainte («load-carrying framework model»). Le deuxième s'applique au cas où la déformation se concentre presque uniquement dans la phase incompétente («two bock model»). La transition d'un modèle partiel à l'autre dépend des propriétés physiques de ces deux phases. Lors d'une déformation progressive cette transition se déplace dans un premier temps vers les plus grandes teneurs en matériau moins compétent, en raison de l'accroissement de la différence de compétence. Puis elle glisse, au contraire, vers les plus petites teneurs en raison du développement d'un rubanement compositionnel d'origine mécanique. Finalement la rhéologie d'une roche ainsi entièrement rubanée est déterminée essentiellement par la rhéologie du matériau le moins compétent.
    Notes: Zusammenfassung Basierend auf empirischen und theoretischen Arbeiten wird ein Modell für zwei- und mehrphasige Gesteine vorgestellt, mit dem die Gesamt-Rheologie als Funktion der Rheologien der einzelnen Phasen, ihren volumenmäßigen Anteilen am Gesamtgestein und ihrer geometrischen Verteilung formuliert werden kann. Das Modell entsteht durch die Verbindung zweier Teil-Modelle. Das eine nimmt ein tragendes Gerüst, aufgebaut durch härtere, vorwiegend spröd bis kataklastisch deformierende Mineralien an. Das zweite gilt für den Bereich, wo die Verformung vollständig durch weiche Komponenten aufgenommen wird. Der Übergang vom Gültigkeitsbereich des einen in denjenigen des anderen Teilmodells ist eine Funktion der Materialeigenschaften der beteiligten Mineralien. Er verlagert sich mit zunehmender Deformation zuerst in Richtung höherer, dann in Richtung niedrigerer Anteile von weicheren Komponenten, bedingt einerseits durch einen zunehmenden Kompetenzkontrast, andererseits durch die zunehmende, mechanisch bedingte Ausbildung einer Stoffbänderung. Die Rheologie des schlußendlich vollständig gebänderten Gesteins wird weitgehendst von der Rheologie der weichsten Komponente kontrolliert.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1432-072X
    Keywords: Bradyrhizobium ; Gene cloning ; Heme ; Marker exchange mutagenesis ; Nitrogen fixation ; Respiration ; Symbiosis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Random and site-directed Tn5-induced mutagenesis of Bradyrhizobium japonicum yielded two mutations, one in strain 2960 and the other in strain 2606::Tn5-20, which mapped close to each other but in separate genes. The corresponding wild-type genes were cloned, and their approximate location on the cloned DNA was determined. Mutant 2960 was Fix- and formed green nodules on soybean, whereas strain 2606::Tn5-20 had ca. 4% of wild-type Fix activity and formed white nodules. Cytochrome oxidase assays (Nadi tests) showed a negative reaction with both mutants, indicating a functional deficiency of cytochrome c or its terminal oxidase or both. However, the mutants grew well under aerobic conditions on minimal media with different carbon sources. Furthermore, mutant 2960 had a reduced activity in hydrogen uptake, was unable to grow anaerobically with nitrate as the terminal electron acceptor and 2960-infected soybean nodules contained little, if any, functional leghemoglobin. Southern blot analysis showed that a B. japonicum heme biosynthesis mutant [strain LO505: O'Brian MR, Kirshbom PM, Maier RJ (1987) Proc Natl Acad Sci USA 84: 8390–8393] had its mutation close to the Tn5 insertion site of our mutant 2606::Tn5-20. This finding, combined with the observed phenotypes, suggested that the genes affected in mutants 2960 and 2606::Tn5-20 were involved in some steps of heme biosynthesis thus explaining the pleiotropic respiratory deficiencies of the mutants. Similar to strain LO505, the mutant 2606::Tn5-20 (but not 2960) was defective in the activity of protoporphyrinogen IX oxidase which catalyzes the penultimate step in the heme biosynthesis pathway. This suggests that one of the two cloned genes may code for this enzyme.
    Type of Medium: Electronic Resource
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  • 9
  • 10
    Publication Date: 1989-10-01
    Print ISSN: 0022-5193
    Electronic ISSN: 1095-8541
    Topics: Biology
    Published by Elsevier
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